Questions/p-block Group 13 & 14/ Why does $$PbI_4$$...
Chemical Properties of G14p-block Group 13 & 14

Why does PbI4PbI_4 not exist?

Expert Answer

The PbIPb-I bond formed would be weak due to size mismatch, but mainly because Iodide ( II^- ) is a strong reducing agent and reduces Pb4+Pb^{4+}toPb2+Pb^{2+}while being oxidized toI2I_2 .

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