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Inorganic Chemistry

p-block Group 13 & 14

Browse 121 questions on p-block Group 13 & 14. Click on any question to view the detailed answer and explanation.

What is the general valence electronic configuration of Group 13?

General Properties of Group 13

Name the elements in the Boron Family.

General Properties of Group 13

Which element is the most abundant metal in the earth's crust?

General Properties of Group 13

Why does Boron have high melting and boiling points?

Physical Properties

What is the trend for atomic radius in Group 13?

Physical Properties

Why is the atomic radius of GaGa smaller than AlAl?

Physical Properties

State the trend for 1st Ionisation Enthalpy in Group 13.

Chemical Properties of G13

Why does TlTl have a higher ionisation enthalpy than AlAl?

Chemical Properties of G13

What is the electronegativity trend for Group 13?

General Properties of Group 13

Which Group 13 element has the lowest melting point?

Physical Properties

Why can Gallium be used in high-temperature thermometry?

Physical Properties

Which Group 13 element forms only covalent compounds?

General Properties of Group 13

What oxidation states are shown by Gallium, Indium, and Thallium?

Oxidation State & Inert Pair Effect

How does the stability of the +3+3 oxidation state change down Group 13?

Oxidation State & Inert Pair Effect

How does the stability of the +1+1 oxidation state change down Group 13?

Oxidation State & Inert Pair Effect

What is the "Inert Pair Effect"?

Oxidation State & Inert Pair Effect

Which is more stable: Tl+Tl^+ or Tl3+Tl^{3+}?

Oxidation State & Inert Pair Effect

Which is more ionic: compounds in +1+1 or +3+3 oxidation state?

Oxidation State & Inert Pair Effect

What products are formed when Group 13 elements react with air?

Chemical Properties of G13

Why is Aluminium stable in air and water?

Chemical Properties of G13

What is the trend for the acidic nature of Group 13 oxides?

Chemical Properties of G13

What happens when Boron is fused with alkali?

Chemical Properties of G13

What is the nature of AlAl and GaGa oxides?

Chemical Properties of G13

Arrange the boron trihalides ( BF3BF_3 , BCl3BCl_3 , BBr3BBr_3 , BI3BI_3 ) in increasing order of Lewis acidic strength.

Chemical Properties of G14

Why is BF3BF_3 the weakest acid despite Fluorine being the most electronegative halogen?

Chemical Properties of G15

What is the formula of the Hexaaqua aluminium (III) ion?

Structure & Formulas

What is the formula of the Tetrahydroxy aluminate (III) ion?

Structure & Formulas

The most common ore of Boron.

Structure & Formulas

Similar to Borax but with less water of crystallization.

Structure & Formulas

A calcium borate ore.

Structure & Formulas

Naturally occurring boric acid found in volcanic vents.

Structure & Formulas

Which Group 13 element does not form trihalides?

Chemical Properties of G13

Are Group 13 fluorides ionic or covalent?

Chemical Properties of G13

What is the nature of anhydrous AlCl3AlCl_3?

Chemical Properties of G13

Why is a solution of AlCl3AlCl_3 acidic?

Chemical Properties of G13

What is the Lewis acid strength order for Boron trihalides?

Chemical Properties of G13

Why is BF3BF_3 a weaker Lewis acid than BCl3BCl_3?

Chemical Properties of G13

What is the maximum covalency of Boron?

General Properties of Group 13

Why can other Group 13 elements show a covalency of 6?

General Properties of Group 13

With which element does Boron show a diagonal relationship?

General Properties of Group 13

How does the reactivity of Boron differ from Al towards air ?

Chemical Properties of G13

What are the conditions for the laboratory preparation of Diborane?

Reactions of Diborane

What is the industrial method for preparing Diborane?

Reactions of Diborane

What happens when Diborane (B2H6B_2H_6) reacts with water?

Reactions of Diborane

What is "Inorganic Benzene"?

Reactions of Diborane

How is Borazine formed?

Reactions of Diborane

What types of bonds are in Diborane?

Reactions of Diborane

What is the correct chemical formula for Borax?

Borax

Borax is a light brown crystalline solid, which dissolves in water to give a neutral solution - True/False

Borax

What is "Borax glass"?

Borax

Borax Bead Test (Action of Heat) What happens when Borax is heated strongly on a platinum loop?

Borax

What are the components of a "Borax Bead"?

Borax

What is the color of the Cobalt borax bead?

Borax

What is the color of the Chromium borax bead?

Borax

Is Orthoboric acid a protic acid?

Orthoboric acid

How does Orthoboric acid act as an acid?

Orthoboric acid

What is the structure of Orthoboric acid?

Orthoboric acid

What happens when H3BO3H_3BO_3 is heated to 100C100^\circ C?

Orthoboric acid

Orthoboric acid has layered structures with hexagon rings. How many atoms are these in one hexagon ring ?

Orthoboric acid

Why can't H3BO3H_3BO_3 be titrated with NaOHNaOH directly, and how does adding vicinal cis-diols (like glycerol or catechol) facilitate the titratio...

Orthoboric acid

How is Boric Acid prepared from Borax?

Orthoboric acid

Describe the reaction of Diborane ( B2H6B_2H_6 ) with air. Is it endothermic or exothermic?

Reactions of Diborane

What products are obtained when Diborane is treated with water?

Reactions of Diborane

What is the product of heating Orthoboric acid to red heat?

Orthoboric acid

Above what temperature does AlCl3AlCl_3 exist as a monomer?

Aluminium & its compounds

What is the hybridization of AlAl in the Al2Cl6Al_2Cl_6 dimer?

Aluminium & its compounds

What is the hybridization of AlAl in the AlCl3AlCl_3 monomer?

Aluminium & its compounds

Name the elements in Group 14 (Carbon Family).

General Properties of Group 14

What is the valence electronic configuration of Group 14?

General Properties of Group 14

Which Group 14 elements are non-metals?

General Properties of Group 14

What is the trend for melting points in Group 14?

Physical Properties of Group 14

Why does the 1st Ionisation Enthalpy increase from SnSn to PbPb?

Physical Properties of Group 14

What are the common oxidation states for Group 14?

Oxidation State & Inert Pair Effect

What is the stability order for the +4+4 oxidation state in Group 14?

Oxidation State & Inert Pair Effect

What is the stability order for the +2+2 oxidation state in Group 14?

Oxidation State & Inert Pair Effect

Why does Carbon show the maximum property of catenation?

Chemical Properties of Group 14

Why do the first elements of p-block groups (like B, C, N) differ in reactivity from the rest of their group?

General Properties of Group 13

Why does Aluminium show only the +3 oxidation state and not +1?

Oxidation State & Inert Pair Effect

Which reactions prove that Aluminium is amphoteric?

Aluminium & its compounds

Why do white fumes appear around a bottle of anhydrous aluminium chloride?

Aluminium & its compounds

State the specific uses of Boron fibres and the 10B^{10}B isotope.

General Properties of Group 13

List the major amphoteric oxides and hydroxides for Boron and Carbon families.

Chemical Properties of G13

Why is Lead (Pb) unaffected by water?

Chemical Properties of G14

Why does PbI4PbI_4 not exist?

Chemical Properties of G14

Most Group 14 tetrahalides ( MX4MX_4 ) are covalent. Which ones are exceptions (ionic)?

Chemical Properties of G14

Why does SiCl4SiCl_4 hydrolyse easily while CCl4CCl_4 does not?

Chemical Properties of G14

What is the primary use of Silica Gel?

General Properties of Group 14

Why is CO2CO_2 a gas but SiO2SiO_2 a high-melting solid?

Structure & Formulas

What is the hybridization of Carbon in Diamond?

Carbon & its compounds

What is the CCC-C bond length in Diamond?

Carbon & its compounds

Why is Diamond an electrical insulator?

Carbon & its compounds

What is the hybridization of Carbon in Graphite?

Carbon & its compounds

What is the distance between layers in Graphite?

Carbon & its compounds

Why is Graphite a good conductor of electricity?

Carbon & its compounds

What is the CCC-C bond length in Graphite?

Carbon & its compounds

What are Fullerenes?

Carbon & its compounds

How many hexagon and pentagon rings are in C60C_{60}?

Carbon & its compounds

What is the hybridization of Carbon in Fullerenes?

Carbon & its compounds

Which allotrope of Carbon is thermodynamically most stable?

Carbon & its compounds

What is Graphene?

Carbon & its compounds

Why is Carbon's maximum covalency limited to four?

Carbon & its compounds

What is the acidity trend for Group 14 dioxides?

Chemical Properties of Group 14

Which Group 14 dioxides are amphoteric?

Chemical Properties of Group 14

What happens when SiH4SiH_4 reacts with air?

Chemical Properties of Group 14

What is the stability trend for Group 14 tetrahalides?

Chemical Properties of Group 14

What is the product of hydrolysis of SiCl4SiCl_4?

Chemical Properties of Group 14

What is "Water gas" or "Synthesis gas"?

Carbon & its compounds

What is "Producer gas"?

Carbon & its compounds

Why is Carbon Monoxide (COCO) poisonous?

Carbon & its compounds

What is "Dry Ice"?

Carbon & its compounds

What is the structure of Silica (SiO2SiO_2)?

Structure & Formulas

What percentage of the Earth's crust is made of Silica and silicates?

General Properties of Group 14

What are Silicones?

Silicone and Silicates

Which silicone monomer forms cross-linked polymers?

Silicone and Silicates

What is used to terminate the chain in silicone polymerization?

Silicone and Silicates

What is the basic unit of all silicates?

Silicone and Silicates

Give an example of an Orthosilicate.

Silicone and Silicates

What is the discrete unit in Pyrosilicates?

Silicone and Silicates

How many oxygen atoms are shared in Cyclic Silicates?

Silicone and Silicates

What is the formula of the cyclic silicate ion with three SiSi atoms?

Silicone and Silicates

Which Group 13 element has a poor shielding effect of d-electrons?

General Properties of Group 13