Questions/p-block Group 13 & 14/Why does $$SiCl_4$$...
Chemical Properties of G14p-block Group 13 & 14

Why does SiCl4SiCl_4 hydrolyse easily while CCl4CCl_4 does not?

Expert Answer

Carbon lacks d-orbitals to accept lone pairs from water molecules. Silicon has vacant 3d-orbitals that can accept lone pairs from H2OH_2O , initiating hydrolysis to form Si(OH)4Si(OH)_4 .

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