JEE Main · 2024 · Shift-IIeasyALCO-005

Common name of Benzene-1, 2-diol is

Alcohols, Phenols & Ethers · Class 12 · JEE Main Previous Year Question

Question

Common name of Benzene-1, 2-diol is

Options
  1. a

    quinol

  2. b

    resorcinol

  3. c

    catechol

  4. d

    o-cresol

Correct Answerc

catechol

Detailed Solution

Step 1: Understand the compound

Benzene-1,2-diol is a benzene ring with two \ceOH\ce{-OH} groups on adjacent (1,2-position = ortho) carbons.

Step 2: Recall common names of dihydroxybenzenes

The three dihydroxybenzene isomers have specific common names:

| IUPAC Name | Position | Common Name | |---|---|---| | Benzene-1,2-diol | ortho (1,2) | Catechol | | Benzene-1,3-diol | meta (1,3) | Resorcinol | | Benzene-1,4-diol | para (1,4) | Quinol (Hydroquinone) |

Step 3: Eliminate wrong options

  • Quinol = benzene-1,4-diol (para isomer) → option (a) wrong
  • Resorcinol = benzene-1,3-diol (meta isomer) → option (b) wrong
  • o-Cresol = 2-methylphenol (has a methyl group, not a second OH) → option (d) wrong

Answer: Catechol = Benzene-1,2-diol ✓

Key Points to Remember:

  • Catechol = ortho (1,2); Resorcinol = meta (1,3); Hydroquinone/Quinol = para (1,4)
  • A simple mnemonic: C-R-Q = ortho-meta-para (alphabetical C before R before Q)
  • o-Cresol has -CH3 + -OH, not two -OH groups.

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