39 JEE Main PYQs · Class 12

JEE Main PYQs — Alcohols, Phenols & Ethers

39 previous year questions from JEE Main on Alcohols, Phenols & Ethers. Each question shows the year, shift, full options, correct answer, and a detailed solution by Paaras Sir.

2024

15 questions
easyShift-IIALCO-005

Common name of Benzene-1, 2-diol is

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hardShift-IALCO-015

The ascending order of acidity of -OH group in the following compounds is:

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easyShift-IIALCO-016

Phenolic group can be identified by a positive:

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hardShift-IIALCO-017

The final product A, formed in the following reaction sequence is: Ph-CH=CH2 (i) BH3; (ii) H2O2,OH- intermediate (iii) HBr; (iv) Mg, ether, then HCHO/H3O+ A

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mediumShift-IALCO-021

Phenol treated with chloroform in presence of sodium hydroxide, which further hydrolysed in presence of an acid results in:

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mediumShift-IIALCO-022

Salicylaldehyde is synthesized from phenol, when reacted with

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hardShift-IIALCO-023

Product A and B formed in the following set of reactions are:

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hardShift-IIALCO-026

Identify A and B in the following reaction sequence. Bromobenzene Conc. HNO3 (excess) A (i) NaOH; (ii) HCl B

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hardShift-IIALCO-028

CH3-CH2-CH2-Br + NaOH C2H5OH Product A Product A undergoes the following two reactions: Consider the above reactions, identify product B and product C.

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hardShift-IALCO-029

Identify compound (Z) in the following reaction sequence: C6H5Cl + NaOH 623 K, 300 atm X HCl Y Conc. HNO3 Z

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hardShift-IALCO-033

In Reimer-Tiemann reaction, phenol is converted into salicylaldehyde through an intermediate. The structure of the intermediate is:

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hardShift-IALCO-034

Identify the major products A and B respectively in the following set of reactions:

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mediumShift-IIALCO-035

Which one of the following compounds will readily react with dilute NaOH?

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hardShift-IALCO-037

For the given compounds, the correct order of increasing pKa value is:

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hardShift-IALCO-038

Identify the product A and product B in the following set of reactions: CH3-CH=CH2 H2O, H+ Major product A CH3-CH=CH2 (i) (BH3)2; (ii) H2O2, OH- Major product B

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2023

13 questions
hardShift-IALCO-039

An organic compound "A" with empirical formula CnH2nO gives sooty flame on burning. Its reaction with bromine solution in low polarity solvent results in high yield of B. B is:

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hardShift-IALCO-040

In a reaction, reagents X and Y are respectively used to convert salicylic acid: Reagents X and Y are respectively:

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mediumShift-IIALCO-041

Incorrect method of preparation for alcohols from the following is:

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hardShift-IALCO-042

Decreasing order of dehydration of the following alcohols is:

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hardShift-IIALCO-043

The strongest acid from the following is:

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hardShift-IIALCO-044

Find out the major product for the following reaction:

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hardShift-IIALCO-045

H3C-CH2-CH(OH)-CH3 (i) NaI, H3PO4; (ii) Mg, dry ether; (iii) D2O Product [X] Product [X] formed in the above reaction is:

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hardShift-IALCO-046

In the following reaction, the left hand side and right hand side rings are named as A and B respectively. They undergo ring expansion. The correct statement for this process is:

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hardShift-IALCO-047

Identify the incorrect option from the following:

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hardShift-IALCO-048

In the following reaction sequence, identify the major product R:

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hardShift-IIALCO-050

Find out the major products from the following reactions:

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hardShift-IALCO-051

The increasing order of pKa for the following phenols is: (1) 2,4-Dinitrophenol (2) 4-Nitrophenol (3) 2,4,5-Trimethylphenol (4) Phenol (5) 3-Chlorophenol

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hardShift-IIALCO-052

The correct order for acidity of the following hydroxyl compounds is:

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JEE Main Alcohols, Phenols & Ethers PYQs — 39 Questions with Solutions | Canvas Classes