JEE Main · 2020 · Shift-IhardALCO-151

The major product of the following reaction is:

Alcohols, Phenols & Ethers · Class 12 · JEE Main Previous Year Question

Question

The major product of the following reaction is: image

Options
  1. a

    image

  2. b

    image

  3. c

    image

  4. d

    image

Correct Answerb

image

Detailed Solution

Step 1: Identify the starting material

The starting material is a diene, treated with an acid catalyst (like \ceH2SO4\ce{H2SO4} or \ceHCl\ce{HCl}) that promotes cyclization.

Step 2: Identify the reaction type

For a diene with an appropriate geometry, intramolecular reaction via protonation gives a cyclic product through:

  1. Protonation of one double bond → carbocation
  2. Intramolecular attack by the other double bond
  3. Ring closure → cyclic product image Answer: Option (b)

Key Points to Remember:

  • Intramolecular electrophilic addition of dienes favors 5- or 6-membered ring formation
  • Proton-catalyzed cyclization follows Markovnikov's rule at each step
  • Ring closure is kinetically favored for 5- and 6-membered rings (Baldwin's rules)

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