The major product of the following reaction is:
Alcohols, Phenols & Ethers · Class 12 · JEE Main Previous Year Question
The major product of the following reaction is:
- a
- b✓
- c
- d
Step 1: Identify the starting material
The starting material is a diene, treated with an acid catalyst (like or ) that promotes cyclization.
Step 2: Identify the reaction type
For a diene with an appropriate geometry, intramolecular reaction via protonation gives a cyclic product through:
- Protonation of one double bond → carbocation
- Intramolecular attack by the other double bond
- Ring closure → cyclic product
Answer: Option (b)
Key Points to Remember:
- Intramolecular electrophilic addition of dienes favors 5- or 6-membered ring formation
- Proton-catalyzed cyclization follows Markovnikov's rule at each step
- Ring closure is kinetically favored for 5- and 6-membered rings (Baldwin's rules)
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