JEE Main · 2019 · Shift-IIeasyBOND-123

Among the following species, the diamagnetic molecule is:

Chemical Bonding · Class 11 · JEE Main Previous Year Question

Question

Among the following species, the diamagnetic molecule is:

Options
  1. a

    CO

  2. b

    B2\mathrm{B_2}

  3. c

    O2\mathrm{O_2}

  4. d

    NO

Correct Answera

CO

Detailed Solution

🧠 Diamagnetic = all electrons paired. Use MO theory for each species.

🗺️ Check unpaired electrons:

| Species | Total e⁻ | Unpaired e⁻ | Magnetic | |---------|-----------|------------|---------| | CO | 14 (isoelectronic with N2\mathrm{N_2}) | 0 | Diamagnetic ✓ | | B2\mathrm{B_2} | 10 | 2 (in degenerate π2p\pi_{2p}) | Paramagnetic | | O2\mathrm{O_2} | 16 | 2 (in degenerate π2p\pi^*_{2p}) | Paramagnetic | | NO | 15 | 1 | Paramagnetic |

⚡ CO has the same number of electrons as N2\mathrm{N_2} (both 14e), so its MO configuration is identical: all electrons paired → BO = 3, diamagnetic.

Answer: CO\boxed{\text{Answer: CO}}

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