JEE Main · 2021 · Shift-IIeasyBOND-112

In the following, the correct bond order sequence is:

Chemical Bonding · Class 11 · JEE Main Previous Year Question

Question

In the following, the correct bond order sequence is:

Options
  1. a

    O22>O2+>O2>O2\mathrm{O_2^{2-} > O_2^+ > O_2^- > O_2}

  2. b

    O2+>O2>O22>O2\mathrm{O_2^+ > O_2^- > O_2^{2-} > O_2}

  3. c

    O2+>O2>O2>O22\mathrm{O_2^+ > O_2 > O_2^- > O_2^{2-}}

  4. d

    O2>O2>O22>O2+\mathrm{O_2 > O_2^- > O_2^{2-} > O_2^+}

Correct Answerc

O2+>O2>O2>O22\mathrm{O_2^+ > O_2 > O_2^- > O_2^{2-}}

Detailed Solution

🧠 Bond order is proportional to bond strength. For the oxygen species, every additional electron enters an antibonding π\pi^* orbital.

| Species | e | BO | |---|---|---| | \ceO2+\ce{O2+} | 15 | 2.5 | | \ceO2\ce{O2} | 16 | 2 | | \ceO2\ce{O2-} | 17 | 1.5 | | \ceO22\ce{O2^{2-}} | 18 | 1 |

Decreasing bond order: \ceO2+>O2>O2>O22\ce{O2+ > O2 > O2^- > O2^{2-}}

Answer: (c) \ceO2+>O2>O2>O22\boxed{\text{Answer: (c) } \ce{O2^+ > O2 > O2^- > O2^{2-}}}

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