The bond order and magnetic behaviour of O2- ion are, respectively:
Chemical Bonding · Class 11 · JEE Main Previous Year Question
The bond order and magnetic behaviour of ion are, respectively:
- a
1.5 and diamagnetic
- b✓
1.5 and paramagnetic
- c
2 and diamagnetic
- d
1 and paramagnetic
1.5 and paramagnetic
🧠 (superoxide ion) has 17 electrons. Apply MO theory.
has 16e and BO = 2. Adding one electron goes into the antibonding orbital:
: ...\pi_{2p}^4\pi^*_{2p}^3
The level now has 3 electrons across 2 degenerate orbitals → one orbital is full (2e), one has 1e → 1 unpaired electron → paramagnetic.
⚡ Rule of thumb: species BO: (2.5) → (2) → (1.5) → (1). Each added electron reduces BO by 0.5.
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