JEE Main · 2021 · Shift-IImediumBOND-031

The bond order and magnetic behaviour of O2- ion are, respectively:

Chemical Bonding · Class 11 · JEE Main Previous Year Question

Question

The bond order and magnetic behaviour of O2\mathrm{O_2^-} ion are, respectively:

Options
  1. a

    1.5 and diamagnetic

  2. b

    1.5 and paramagnetic

  3. c

    2 and diamagnetic

  4. d

    1 and paramagnetic

Correct Answerb

1.5 and paramagnetic

Detailed Solution

🧠 \ceO2\ce{O2-} (superoxide ion) has 17 electrons. Apply MO theory.

\ceO2\ce{O2} has 16e and BO = 2. Adding one electron goes into the antibonding π2p\pi^*_{2p} orbital:

\ceO2\ce{O2-}: ...\pi_{2p}^4\pi^*_{2p}^3

BO=bondingantibonding2=1072=1.5\text{BO} = \frac{\text{bonding} - \text{antibonding}}{2} = \frac{10 - 7}{2} = 1.5

The π2p\pi^*_{2p} level now has 3 electrons across 2 degenerate orbitals → one orbital is full (2e), one has 1e → 1 unpaired electron → paramagnetic.

⚡ Rule of thumb: \ceO2\ce{O2} species BO: \ceO2+\ce{O2+}(2.5) → \ceO2\ce{O2}(2) → \ceO2\ce{O2-}(1.5) → \ceO22\ce{O2^{2-}}(1). Each added electron reduces BO by 0.5.

Answer: (b) 1.5 and paramagnetic\boxed{\text{Answer: (b) 1.5 and paramagnetic}}

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