JEE Main · 2024 · Shift-IIhardCEQ-019

A(g) B(g) + C2(g). The correct relationship between KP, and equilibrium pressure P is

Chemical Equilibrium · Class 11 · JEE Main Previous Year Question

Question

A(g)B(g)+C2(g)\mathrm{A_{(g)} \rightleftharpoons B_{(g)} + \frac{C}{2_{(g)}}}. The correct relationship between KPK_P, α\alpha and equilibrium pressure PP is

Options
  1. a

    KP=α1/2P1/2(2+α)1/2K_P = \frac{\alpha^{1/2} P^{1/2}}{(2+\alpha)^{1/2}}

  2. b

    KP=α3/2P1/2(2+α)1/2(1α)K_P = \frac{\alpha^{3/2} P^{1/2}}{(2+\alpha)^{1/2}(1-\alpha)}

  3. c

    KP=α1/2P3/2(2+α)3/2K_P = \frac{\alpha^{1/2} P^{3/2}}{(2+\alpha)^{3/2}}

  4. d

    KP=α1/2P1/2(2+α)3/2K_P = \frac{\alpha^{1/2} P^{1/2}}{(2+\alpha)^{3/2}}

Correct Answerb

KP=α3/2P1/2(2+α)1/2(1α)K_P = \frac{\alpha^{3/2} P^{1/2}}{(2+\alpha)^{1/2}(1-\alpha)}

Detailed Solution

Step 1 — Set up ICE table (start with 1 mol A):

| | A | B | C/2 | Total | |--|--|--|--|--| | Initial | 1 | 0 | 0 | 1 | | Change | α-\alpha | +α+\alpha | +α/2+\alpha/2 | | | Equil. | 1α1-\alpha | α\alpha | α/2\alpha/2 | 1+α/21 + \alpha/2 |

Step 2 — Mole fractions and partial pressures: xA=1α1+α/2,xB=α1+α/2,xC=α/21+α/2x_A = \frac{1-\alpha}{1+\alpha/2}, \quad x_B = \frac{\alpha}{1+\alpha/2}, \quad x_C = \frac{\alpha/2}{1+\alpha/2}

Multiply by PP: PA=(1α)P1+α/2P_A = \frac{(1-\alpha)P}{1+\alpha/2}, PB=αP1+α/2P_B = \frac{\alpha P}{1+\alpha/2}, PC=αP/21+α/2P_C = \frac{\alpha P/2}{1+\alpha/2}

Step 3 — Write KPK_P: KP=PBPC1/2PA=αP1+α/2(αP/21+α/2)1/2(1α)P1+α/2=α(α/2)1/2P1/2(1α)(1+α/2)1/2K_P = \frac{P_B \cdot P_C^{1/2}}{P_A} = \frac{\frac{\alpha P}{1+\alpha/2} \cdot \left(\frac{\alpha P/2}{1+\alpha/2}\right)^{1/2}}{\frac{(1-\alpha)P}{1+\alpha/2}} = \frac{\alpha \cdot (\alpha/2)^{1/2} \cdot P^{1/2}}{(1-\alpha)(1+\alpha/2)^{1/2}}

With 1+α/2=(2+α)/21 + \alpha/2 = (2+\alpha)/2: KP=α3/2P1/221/2(1α)(2+α2)1/2=α3/2P1/2(1α)(2+α)1/2K_P = \frac{\alpha^{3/2} P^{1/2}}{2^{1/2}(1-\alpha) \cdot \left(\frac{2+\alpha}{2}\right)^{1/2}} = \frac{\alpha^{3/2} P^{1/2}}{(1-\alpha)(2+\alpha)^{1/2}}

Answer: Option (2)

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