For compound having the formula GaAlCl4, the correct option from the following is:
Classification of Elements & Periodicity · Class 11 · JEE Main Previous Year Question
For compound having the formula GaAlCl, the correct option from the following is:
- a
Ga is coordinated with Cl in
- b✓
Ga is more electronegative than Al and is present as a cationic part of the salt
- c
Cl forms bond with both Al and Ga in
- d
Oxidation state of Ga in the salt is +3
Ga is more electronegative than Al and is present as a cationic part of the salt
1. Structural Composition: The compound is an ionic salt rather than a covalent molecule. It is correctly formulated as: Cation: Gallium exists in the oxidation state (). This is a result of the Inert Pair Effect, where the electrons remain unshared due to poor shielding by the electrons.
Anion: Aluminum is the central atom in the tetrahedral complex anion , where it exists in its stable oxidation state.
2. Electronegativity Anomaly In Group 13, electronegativity does not follow a perfectly descending trend. Due to the d-block contraction (Transition Contraction), the effective nuclear charge () of Gallium is higher than that of Aluminum. Gallium follows the series, and the poor shielding of -electrons causes the nucleus to hold the valence electrons more tightly.
The Pauling electronegativity values are: \text{Electronegativity of Al } (\chi_{Al}) \approx 1.51$$\text{Electronegativity of Ga } (\chi_{Ga}) \approx 1.6.
Evaluation of Options: Option A: Incorrect. is an isolated cation in the lattice; it is not the central coordinating atom for the ligands.
Option B: Correct. As shown above, is more electronegative than and acts as the cation ().
Option C: Incorrect. is covalently bonded to within the unit. The interaction between and is predominantly ionic.
Option D: Incorrect. The oxidation state of Gallium in this specific compound is .
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