JEE Main · 2023 · Shift-IhardPERI-100

For compound having the formula GaAlCl4, the correct option from the following is:

Classification of Elements & Periodicity · Class 11 · JEE Main Previous Year Question

Question

For compound having the formula GaAlCl4_4, the correct option from the following is:

Options
  1. a

    Ga is coordinated with Cl in \ceGaAlCl4\ce{GaAlCl4}

  2. b

    Ga is more electronegative than Al and is present as a cationic part of the salt \ceGaAlCl4\ce{GaAlCl4}

  3. c

    Cl forms bond with both Al and Ga in \ceGaAlCl4\ce{GaAlCl4}

  4. d

    Oxidation state of Ga in the salt \ceGaAlCl4\ce{GaAlCl4} is +3

Correct Answerb

Ga is more electronegative than Al and is present as a cationic part of the salt \ceGaAlCl4\ce{GaAlCl4}

Detailed Solution

1. Structural Composition: The compound GaAlCl4GaAlCl_4 is an ionic salt rather than a covalent molecule. It is correctly formulated as:[Ga]+[AlCl4][Ga]^+ [AlCl_4]^- Cation: Gallium exists in the +1+1 oxidation state (Ga+Ga^+). This is a result of the Inert Pair Effect, where the 4s24s^2 electrons remain unshared due to poor shielding by the 3d103d^{10} electrons.

Anion: Aluminum is the central atom in the tetrahedral complex anion [AlCl4][AlCl_4]^-, where it exists in its stable +3+3 oxidation state.

2. Electronegativity Anomaly In Group 13, electronegativity does not follow a perfectly descending trend. Due to the d-block contraction (Transition Contraction), the effective nuclear charge (ZeffZ_{eff}) of Gallium is higher than that of Aluminum. Gallium follows the 3d103d^{10} series, and the poor shielding of dd-electrons causes the nucleus to hold the valence electrons more tightly.

The Pauling electronegativity values are: \text{Electronegativity of Al } (\chi_{Al}) \approx 1.51$$\text{Electronegativity of Ga } (\chi_{Ga}) \approx 1.6.

Evaluation of Options: Option A: Incorrect. Ga+Ga^+ is an isolated cation in the lattice; it is not the central coordinating atom for the ClCl ligands.

Option B: Correct. As shown above, GaGa is more electronegative than AlAl and acts as the cation (Ga+Ga^+).

Option C: Incorrect. ClCl is covalently bonded to AlAl within the [AlCl4][AlCl_4]^- unit. The interaction between Ga+Ga^+ and ClCl^- is predominantly ionic.

Option D: Incorrect. The oxidation state of Gallium in this specific compound is +1+1.

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