JEE Main · 2021 · Shift-IImediumPERI-033

The characteristics of elements X, Y and Z with atomic numbers, respectively, 33, 53 and 83 are:

Classification of Elements & Periodicity · Class 11 · JEE Main Previous Year Question

Question

The characteristics of elements X, Y and Z with atomic numbers, respectively, 33, 53 and 83 are:

Options
  1. a

    X and Y are metalloids and Z is a metal

  2. b

    X is a metalloid, Y is a non-metal and Z is a metal

  3. c

    X, Y and Z are metals

  4. d

    X and Z are non-metals and Y is a metalloid

Correct Answerb

X is a metalloid, Y is a non-metal and Z is a metal

Detailed Solution

🧠 Identify each element from its atomic number, then place it on the metal–non-metal map The trick is to know where the staircase line cuts: elements like B, Si, Ge, As, Sb, Te are metalloids. Above the line is non-metal, below is metal.

🗺️ Identify X, Y, Z Z=33Z = 33: Arsenic (As). Group 15, Period 4. Sits right on the staircase → metalloid. Z=53Z = 53: Iodine (I). Group 17, Period 5. Halogen, well above the staircase → non-metal. Z=83Z = 83: Bismuth (Bi). Group 15, Period 6. Heavy post-transition element below the staircase → metal.

So: X = metalloid, Y = non-metal, Z = metal. That is option (b).

⚠️ The trap Option (a) calls iodine (Z=53Z=53) a metalloid. Iodine looks shiny in solid form and conducts a tiny bit, which fools students. But its chemistry is fully non-metallic — it forms anions like \ceI\ce{I^-} and acidic oxoacids. Don't go by appearance; go by chemistry.

Answer: (b)\boxed{\text{Answer: (b)}} image

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