JEE Main · 2023easyCORD-057

The covalency and oxidation state respectively of boron in [BF4]-, are:

Coordination Compounds · Class 12 · JEE Main Previous Year Question

Question

The covalency and oxidation state respectively of boron in [BF4][\mathrm{BF_4}]^-, are:

Options
  1. a

    3 and 5

  2. b

    3 and 4

  3. c

    4 and 4

  4. d

    4 and 3

Correct Answerd

4 and 3

Detailed Solution

🧠 Covalency vs Oxidation State

Two different concepts:

  • Covalency = total number of bonds the central atom forms (whether normal covalent or coordinate).
  • Oxidation state = formal charge from electronegativity-based electron assignment.

For [BF4][\mathrm{BF_4}]^-: boron is bonded to 4 fluorines (3 normal B–F + 1 coordinate from F\mathrm{F^-}). So covalency = 4. OS calculation: x+4(1)=1x=+3x + 4(-1) = -1 \Rightarrow x = +3.

🗺️ Both Numbers

Covalency. Boron makes 4 bonds in [BF4][\mathrm{BF_4}]^-. Three are formed in BF3\mathrm{BF_3}; the fourth comes from a fluoride donating its lone pair into boron's empty p-orbital (Lewis acid–base adduct). Total bonds at B = 4.

Oxidation state. F is more electronegative than B, so each F takes both bond electrons → F gets OS 1-1. Then x+4(1)=1x=+3x + 4(-1) = -1 \Rightarrow x = +3. So OS = +3.

So pair = (4, +3) → option (4).

The Lewis-Acid Adduct Pattern

BF3\mathrm{BF_3} + F\mathrm{F^-}[BF4][\mathrm{BF_4}]^- is a textbook coordinate bond reaction: covalency rises by 1 (3 → 4) but oxidation state stays at +3. Same pattern for BF3+NH3F3BNH3\mathrm{BF_3 + NH_3 \to F_3B \leftarrow NH_3}: covalency 4, OS +3.

⚠️ Don't Conflate the Two Numbers

Covalency tracks bond count; OS tracks formal charge. Adding a coordinate bond changes covalency but not OS. Many students see four bonds and write OS +4 (option 3) — a common slip on exam day.

Answer: (4) 4 and 3\boxed{\text{Answer: (4) 4 and 3}}

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