The covalency and oxidation state respectively of boron in [BF4]-, are:
Coordination Compounds · Class 12 · JEE Main Previous Year Question
The covalency and oxidation state respectively of boron in , are:
- a
3 and 5
- b
3 and 4
- c
4 and 4
- d✓
4 and 3
4 and 3
🧠 Covalency vs Oxidation State
Two different concepts:
- Covalency = total number of bonds the central atom forms (whether normal covalent or coordinate).
- Oxidation state = formal charge from electronegativity-based electron assignment.
For : boron is bonded to 4 fluorines (3 normal B–F + 1 coordinate from ). So covalency = 4. OS calculation: .
🗺️ Both Numbers
Covalency. Boron makes 4 bonds in . Three are formed in ; the fourth comes from a fluoride donating its lone pair into boron's empty p-orbital (Lewis acid–base adduct). Total bonds at B = 4.
Oxidation state. F is more electronegative than B, so each F takes both bond electrons → F gets OS . Then . So OS = +3.
So pair = (4, +3) → option (4).
⚡ The Lewis-Acid Adduct Pattern
+ → is a textbook coordinate bond reaction: covalency rises by 1 (3 → 4) but oxidation state stays at +3. Same pattern for : covalency 4, OS +3.
⚠️ Don't Conflate the Two Numbers
Covalency tracks bond count; OS tracks formal charge. Adding a coordinate bond changes covalency but not OS. Many students see four bonds and write OS +4 (option 3) — a common slip on exam day.
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