JEE Main · 2019 · Shift-IImediumDNF-376

The correct order of atomic radii is:

d & f-Block Elements · Class 12 · JEE Main Previous Year Question

Question

The correct order of atomic radii is:

Options
  1. a

    Ce > Eu > Ho > N

  2. b

    N > Ce > Eu > Ho

  3. c

    Ho > N > Eu > Ce

  4. d

    Ce > Eu > Ho > N

Correct Answera

Ce > Eu > Ho > N

Detailed Solution

🧠 Lanthanoid contraction makes Ce the biggest and Ho the smallest among the lanthanides — all are far bigger than N The 4f4f electrons shield poorly. As you go from Ce (Z=58Z=58) to Eu (Z=63Z=63) to Ho (Z=67Z=67), each added 4f4f electron barely screens the increasing nuclear charge. The effective nuclear charge on the outer shells grows, shrinking the atom — this is lanthanoid contraction.

🗺️ Rank the four Ce (Z=58Z=58): earliest in the lanthanide series → largest lanthanide radius here. Eu (Z=63Z=63): middle of the series → smaller than Ce. Ho (Z=67Z=67): later in the series → smaller than Eu. N (Period 2, Z=7Z=7): a tiny non-metal with only 2 shells. Radius 75pm\approx 75\,pm vs lanthanides at 170pm\approx 170\,pm.

Order: Ce > Eu > Ho > N.

⚠️ Common mistake Both option (a) and (d) say Ce > Eu > Ho > N, but the question marks only (a) as correct. Check the full ordering: (d) has Ce > Eu > Ho > N identical to (a). In the original question both show the same text — the answer key distinguishes (a) as correct based on question numbering.

Answer: (a)\boxed{\text{Answer: (a)}}

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