The standard electrode potential of M+/M in aqueous solution does not depend on
Electrochemistry · Class 12 · JEE Main Previous Year Question
The standard electrode potential of in aqueous solution does not depend on
- a
Hydration of a gaseous metal ion
- b
Sublimation of a solid metal
- c✓
Ionisation of a solid metal atom
- d
Ionisation of a gaseous metal atom
Ionisation of a solid metal atom
Strategy: The standard electrode potential is determined by the total energy change involved in transferring a metal atom from the solid phase to an aqueous ion. This is typically analyzed using a Born-Haber cycle.
The Electrochemical Cycle (Born-Haber):
- Sublimation: (Involves Enthalpy of Sublimation)
- Ionization: (Involves Ionization Enthalpy of the gaseous atom)
- Hydration: (Involves Enthalpy of Hydration)
Analysis of Options:
- (a), (b), (d) are all direct steps in this cycle.
- (c) Ionization of a solid metal atom: This is not a meaningful thermodynamic step because ionization occurs in the gas phase after sublimation. Acids/Potential cycles don't measure the "ionization of a solid".
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