JEE Main · 2023 · Shift-ImediumEC-053

The standard electrode potential of M+/M in aqueous solution does not depend on

Electrochemistry · Class 12 · JEE Main Previous Year Question

Question

The standard electrode potential of M+/M\mathrm{M^+/M} in aqueous solution does not depend on

Options
  1. a

    Hydration of a gaseous metal ion

  2. b

    Sublimation of a solid metal

  3. c

    Ionisation of a solid metal atom

  4. d

    Ionisation of a gaseous metal atom

Correct Answerc

Ionisation of a solid metal atom

Detailed Solution

Strategy: The standard electrode potential is determined by the total energy change involved in transferring a metal atom from the solid phase to an aqueous ion. This is typically analyzed using a Born-Haber cycle.

The Electrochemical Cycle (Born-Haber):

  1. Sublimation: \ceM(s)M(g)\ce{M(s) \rightarrow M(g)} (Involves Enthalpy of Sublimation)
  2. Ionization: \ceM(g)M+(g)+e\ce{M(g) \rightarrow M^+(g) + e^-} (Involves Ionization Enthalpy of the gaseous atom)
  3. Hydration: \ceM+(g)M+(aq)\ce{M^+(g) \rightarrow M^+(aq)} (Involves Enthalpy of Hydration)

Analysis of Options:

  • (a), (b), (d) are all direct steps in this cycle.
  • (c) Ionization of a solid metal atom: This is not a meaningful thermodynamic step because ionization occurs in the gas phase after sublimation. Acids/Potential cycles don't measure the "ionization of a solid".

Answer: (c) Ionisation of a solid metal atom\boxed{\text{Answer: (c) Ionisation of a solid metal atom}}

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