JEE Main · 2021 · Shift-ImediumGOC-092

Compound with most acidic hydrogen:

General Organic Chemistry (GOC) · Class 11 · JEE Main Previous Year Question

Question

Compound with most acidic hydrogen: image

Options
  1. a

    Option A

  2. b

    Option B

  3. c

    Option C

  4. d

    Option D

Correct Answerb

Option B

Detailed Solution

Step 1: Identifying Active Methylene Compounds Acidity depends on the stability of the conjugate base anion.

  • (B): Propane-1,2,3-tricarboxylate derivative. The hydrogen is alpha to three ester groups. The combined I-I and R-R effects provide massive stabilization.
  • (D): Malononitrile (two \ceCN-\ce{CN} groups). Extremely acidic, but fewer groups than B.
  • (C): Acetone (one carbonyl).
  • (A): Terminal alkyne (spsp CH).

Step 2: Conclusion Option B has three carbonyl-stabilizing groups for a single proton site.

Answer: (b) Option B\boxed{\text{Answer: (b) Option B}}

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