JEE Main · 2021 · Shift-ImediumGOC-089

Correct order of stability of above carbocations is:

General Organic Chemistry (GOC) · Class 11 · JEE Main Previous Year Question

Question

image Correct order of stability of above carbocations is:

Options
  1. a

    A > C > B > D

  2. b

    D > B > C > A

  3. c

    C > A > D > B

  4. d

    D > B > A > C

Correct Answera

A > C > B > D

Detailed Solution

Step 1: Evaluating Carbocation Stability

  • (A) Benzyl Cation: High resonance stabilization from the phenyl ring. (Most stable).
  • (C) Ethyl Cation: Stabilized by hyperconjugation (+I+I and 3 H-atoms). (More stable than vinyl).
  • (B) Vinyl Cation: Positive charge on sp2sp^2 carbon. (Very unstable).
  • (D) Ethynyl Cation: Positive charge on spsp carbon. (Least stable due to high electronegativity of spsp carbon).

Step 2: Conclusion Order: (A) > (C) > (B) > (D).

Answer: (a)\boxed{\text{Answer: (a)}} Here is the complete list of carbocation stability based on real data from reputed organic book.

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