JEE Main · 2024 · Shift-IeasyHC-031

Number of and bonds present in ethylene molecule is respectively:

Hydrocarbons · Class 11 · JEE Main Previous Year Question

Question

Number of σ\sigma and π\pi bonds present in ethylene molecule is respectively:

Options
  1. a

    3 and 1

  2. b

    5 and 2

  3. c

    4 and 1

  4. d

    5 and 1

Correct Answerd

5 and 1

Detailed Solution

Step 1: Draw the structure of ethylene

Ethylene: \ceH2C=CH2\ce{H2C=CH2}

Both carbons are sp2sp^2 hybridized, with a double bond (σ+π\sigma + \pi) between them.

Step 2: Count σ\sigma bonds

  • \ceCH\ce{C-H} bonds: Each carbon has 2 H atoms → 2×2=42 \times 2 = 4 \ceCH\ce{C-H} σ\sigma bonds
  • \ceC=C\ce{C=C} double bond contains 1 σ\sigma bond

Total σ\sigma bonds = 4+1=54 + 1 = \mathbf{5}

Step 3: Count π\pi bonds

  • The \ceC=C\ce{C=C} double bond contains 1 π\pi bond (formed by lateral overlap of pp orbitals)

Total π\pi bonds = 1\mathbf{1}

Step 4: Answer

σ\sigma bonds = 5, π\pi bonds = 1 → Option (d)

Key Points to Remember:

  • Every bond contains at least 1 σ\sigma bond
  • Double bond = 1 σ\sigma + 1 π\pi; Triple bond = 1 σ\sigma + 2 π\pi
  • \ceCH\ce{C-H} bonds are always σ\sigma bonds
  • For \ceCnH2n\ce{CnH_{2n}} (alkene): σ=3n1\sigma = 3n-1... for ethylene (n=2n=2): σ=5\sigma = 5

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