JEE Main · 2024 · Shift-IIeasyHC-034

The incorrect statement regarding the geometrical isomers of 2-butene is:

Hydrocarbons · Class 11 · JEE Main Previous Year Question

Question

The incorrect statement regarding the geometrical isomers of 2-butene is:

Options
  1. a

    cis-2-butene and trans-2-butene are not interconvertible at room temperature.

  2. b

    cis-2-butene has less dipole moment than trans-2-butene.

  3. c

    trans-2-butene is more stable than cis-2-butene.

  4. d

    cis-2-butene and trans-2-butene are stereoisomers.

Correct Answerb

cis-2-butene has less dipole moment than trans-2-butene.

Detailed Solution

Step 1: Analyze each statement about 2-butene geometrical isomers

(a) Not interconvertible at room temperature — TRUE ✓ Interconversion requires breaking the π\pi bond (requires ~250 kJ/mol), which doesn't happen at room temperature.

(b) cis-2-butene has LESS dipole moment than trans-2-buteneFALSE

  • cis-2-butene: both \ceCH3\ce{CH3} on same side → dipole moments addμ>0\mu > 0
  • trans-2-butene: \ceCH3\ce{CH3} on opposite sides → dipole moments cancelμ=0\mu = 0
  • Therefore cis-2-butene has MORE (not less) dipole moment than trans-2-butene

(c) trans-2-butene is more stable — TRUE ✓ Trans isomers have less steric repulsion (bulky groups far apart) → more stable.

(d) They are stereoisomers — TRUE ✓ Geometrical isomers are a type of stereoisomer (same connectivity, different spatial arrangement).

Step 2: Identify the incorrect statement

Statement (b) is incorrect → Option (b)

Key Points to Remember:

  • Dipole moment: cis > trans (for symmetric disubstituted alkenes)
  • Stability: trans > cis (less steric strain)
  • Boiling point: cis > trans (higher dipole → stronger intermolecular forces)
  • Melting point: trans > cis (better crystal packing due to symmetry)

Practice this question with progress tracking

Want timed practice with adaptive difficulty? Solve this question (and hundreds more from Hydrocarbons) inside The Crucible, our adaptive practice platform.

The incorrect statement regarding the geometrical isomers of 2-butene is: (JEE Main 2024) | Canvas Classes