The incorrect statement regarding the geometrical isomers of 2-butene is:
Hydrocarbons · Class 11 · JEE Main Previous Year Question
The incorrect statement regarding the geometrical isomers of 2-butene is:
- a
cis-2-butene and trans-2-butene are not interconvertible at room temperature.
- b✓
cis-2-butene has less dipole moment than trans-2-butene.
- c
trans-2-butene is more stable than cis-2-butene.
- d
cis-2-butene and trans-2-butene are stereoisomers.
cis-2-butene has less dipole moment than trans-2-butene.
Step 1: Analyze each statement about 2-butene geometrical isomers
(a) Not interconvertible at room temperature — TRUE ✓ Interconversion requires breaking the bond (requires ~250 kJ/mol), which doesn't happen at room temperature.
(b) cis-2-butene has LESS dipole moment than trans-2-butene — FALSE ✗
- cis-2-butene: both on same side → dipole moments add →
- trans-2-butene: on opposite sides → dipole moments cancel →
- Therefore cis-2-butene has MORE (not less) dipole moment than trans-2-butene
(c) trans-2-butene is more stable — TRUE ✓ Trans isomers have less steric repulsion (bulky groups far apart) → more stable.
(d) They are stereoisomers — TRUE ✓ Geometrical isomers are a type of stereoisomer (same connectivity, different spatial arrangement).
Step 2: Identify the incorrect statement
Statement (b) is incorrect → Option (b)
Key Points to Remember:
- Dipole moment: cis > trans (for symmetric disubstituted alkenes)
- Stability: trans > cis (less steric strain)
- Boiling point: cis > trans (higher dipole → stronger intermolecular forces)
- Melting point: trans > cis (better crystal packing due to symmetry)
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