The major product P formed in the given reaction is:
Hydrocarbons · Class 11 · JEE Main Previous Year Question
The major product P formed in the given reaction is:
- a
- b
- c
- d✓
Step 1: Identify the Starting Material
From the image: a naphthalene ring with (ethyl), (vinyl), and (methyl ester) substituents.
Step 2: Hot Alkaline KMnO4 Oxidation
Hot alkaline oxidizes:
- Alkyl side chains on benzene ring to
- Vinyl group to (oxidative cleavage)
- Methyl ester hydrolyzes to under alk. conditions
- The naphthalene ring itself may be cleaved to give multiple groups
Step 3: Product P
All oxidizable side chains . The complex oxidation gives a phthalic acid or naphthalenedicarboxylic acid type product (option d from the image).
Key Points:
- Hot alk. : oxidizes all alkyl side chains to
- oxidatively cleaved to
- Ester groups hydrolyze under alkaline conditions
- Naphthalene ring also susceptible to oxidation under harsh conditions
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