JEE Main · 2021 · Shift-ImediumPB11-057

Compound A used as a strong oxidizing agent is amphoteric in nature. It is the part of lead storage batteries. Compound…

p-Block Elements (Class 11) · Class 11 · JEE Main Previous Year Question

Question

Compound A used as a strong oxidizing agent is amphoteric in nature. It is the part of lead storage batteries. Compound A is:

Options
  1. a

    PbO

  2. b

    Pb3O4\mathrm{Pb_3O_4}

  3. c

    PbO2\mathrm{PbO_2}

  4. d

    PbSO4\mathrm{PbSO_4}

Correct Answerc

PbO2\mathrm{PbO_2}

Detailed Solution

Strategy: Identify compound A from its properties: strong oxidising agent, amphoteric, and component of lead-acid batteries.

Step 1: Lead Battery Chemistry In a lead-acid (lead storage) battery:

  • Anode: \cePb\ce{Pb}
  • Cathode: \cePbO2\ce{PbO2} (lead dioxide)
  • Electrolyte: \ceH2SO4\ce{H2SO4}

The cathode material \cePbO2\ce{PbO2} is the compound used in the battery. ✅

Step 2: Properties Verification

  • Strong oxidising agent: \cePbO2\ce{PbO2} contains Pb(IV), a high oxidation state that readily gains electrons (e.g., oxidises \ceHCl\ce{HCl} to \ceCl2\ce{Cl2}). ✅
  • Amphoteric: \cePbO2\ce{PbO2} reacts with acids (giving Pb⁴⁺ salts) and strong bases (giving plumbate \cePbO32\ce{PbO3^{2-}}). ✅
  • Part of lead storage battery: Cathode material. ✅

Answer: (C) \cePbO2\boxed{\text{Answer: (C) }\ce{PbO2}}

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