JEE Main · 2023 · Shift-ImediumPB11-021

During the borax bead test with CuSO4, a blue green colour of the bead was observed in oxidising flame due to the…

p-Block Elements (Class 11) · Class 11 · JEE Main Previous Year Question

Question

During the borax bead test with CuSO4\mathrm{CuSO_4}, a blue green colour of the bead was observed in oxidising flame due to the formation of

Options
  1. a

    Cu3B2\mathrm{Cu_3B_2}

  2. b

    Cu

  3. c

    Cu(BO2)2\mathrm{Cu(BO_2)_2}

  4. d

    CuO

Correct Answerc

Cu(BO2)2\mathrm{Cu(BO_2)_2}

Detailed Solution

Strategy: Identify the blue-green coloured product formed during the borax bead test with CuSO₄ in an oxidising flame.

Step 1: Borax Bead Test — Chemistry When borax (\ceNa2B4O7\ce{Na2B4O7}) is heated, it first melts, then loses water and forms a glassy bead of \ceB2O3\ce{B2O3}: \ceNa2B4O7Δ2NaBO2+B2O3\ce{Na2B4O7 \xrightarrow{\Delta} 2NaBO2 + B2O3}

Step 2: Reaction with CuSO₄ in Oxidising Flame In the oxidising flame, \ceCuSO4\ce{CuSO4} reacts with \ceB2O3\ce{B2O3} to give copper metaborate, which imparts a characteristic blue-green colour: \ceCuSO4+B2O3>Cu(BO2)2+SO3\ce{CuSO4 + B2O3 -> Cu(BO2)2 + SO3}

The blue-green bead is due to \ceCu(BO2)2\ce{Cu(BO2)2} (copper metaborate).

Answer: (C) \ceCu(BO2)2\boxed{\text{Answer: (C) }\ce{Cu(BO2)2}}

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