JEE Main · 2021 · Shift-IImediumPB11-045

The INCORRECT statement regarding the structure of C60 is:

p-Block Elements (Class 11) · Class 11 · JEE Main Previous Year Question

Question

The INCORRECT statement regarding the structure of C60\mathrm{C_{60}} is:

Options
  1. a

    The six-membered rings are fused to both six and five-membered rings.

  2. b

    Each carbon atom forms three sigma bonds.

  3. c

    The five-membered rings are fused only to six-membered rings.

  4. d

    It contains 12 six-membered rings and 24 five-membered rings.

Correct Answerd

It contains 12 six-membered rings and 24 five-membered rings.

Detailed Solution

Strategy: Identify the INCORRECT statement about the structure of \ceC60\ce{C60}.

Step 1: Known Facts about C₆₀

  • \ceC60\ce{C60} contains 20 hexagonal and 12 pentagonal rings. ✅
  • Six-membered rings are fused to both six and five-membered rings. ✅ (Option A is correct)
  • Each carbon is sp2sp^2 hybridised and forms 3 sigma bonds. ✅ (Option B is correct)
  • Five-membered rings are fused only to six-membered rings (no two pentagons are adjacent — isolated pentagon rule). ✅ (Option C is correct)

Step 2: Evaluating Option D Option D claims "12 six-membered rings and 24 five-membered rings." This is wrong — the actual numbers are 20 hexagons and 12 pentagons. The statement has both numbers completely reversed/incorrect. ❌

Answer: (D) It contains 12 six-membered rings and 24 five-membered rings\boxed{\text{Answer: (D) It contains 12 six-membered rings and 24 five-membered rings}}

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The INCORRECT statement regarding the structure of C60 is: (JEE Main 2021) | Canvas Classes