JEE Main · 2022 · Shift-IIeasyPB12-005

Dinitrogen and dioxygen the main constituents of air do not react with each other in atmosphere to form oxides of…

p-Block Elements (Class 12) · Class 12 · JEE Main Previous Year Question

Question

Dinitrogen and dioxygen the main constituents of air do not react with each other in atmosphere to form oxides of nitrogen because

Options
  1. a

    N2\mathrm{N_2} is unreactive in the condition of atmosphere.

  2. b

    Oxides of nitrogen are unstable.

  3. c

    Reaction between them can occur in the presence of a catalyst.

  4. d

    The reaction is endothermic and require very high temperature.

Correct Answerd

The reaction is endothermic and require very high temperature.

Detailed Solution

Strategy: Consider the thermodynamics and activation energy for the reaction between \ceN2\ce{N2} and \ceO2\ce{O2}.

Step 1: Nitrogen Inertness Nitrogen (\ceN2)(\ce{N2}) has an extremely high bond dissociation enthalpy (941 kJ/mol)(\approx 941 \text{ kJ/mol}) due to the triple bond (\ceNN)(\ce{N\equiv N}), making it virtually inert at room temperature.

Step 2: Endothermic Nature The reaction \ceN2(g)+O2(g)2NO(g)\ce{N2(g) + O2(g) \rightleftharpoons 2NO(g)} is highly endothermic. It requires very high temperatures (like in lightning or internal combustion engines) to proceed significanty.

Answer: (Option) [d] The reaction is endothermic and require very high temperature\boxed{\text{Answer: (Option) [d] The reaction is endothermic and require very high temperature}}

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