JEE Main · 2025 · Shift-ImediumPB12-126

The group 14 elements A and B have the first ionisation enthalpy values of 708 and 715 kJ mol-1 respectively. The above…

p-Block Elements (Class 12) · Class 12 · JEE Main Previous Year Question

Question

The group 14 elements A and B have the first ionisation enthalpy values of 708 and 715 kJ mol1^{-1} respectively. The above values are lowest among their group members. The nature of their ions A2+\text{A}^{2+} and B4+\text{B}^{4+} respectively is

Options
  1. a

    both reducing

  2. b

    both oxidising

  3. c

    reducing and oxidising

  4. d

    oxidising and reducing

Correct Answerc

reducing and oxidising

Detailed Solution

Step 1: Identify elements A and B

Group 14 elements: C, Si, Ge, Sn, Pb

First ionisation enthalpies (kJ/mol): C(1086) > Si(786) > Ge(762) > Sn(708) > Pb(715)

The two lowest IE values in Group 14 are Sn (708) and Pb (715).

So: A = Sn (IE = 708), B = Pb (IE = 715)

Step 2: Analyse A2+\text{A}^{2+} = \ceSn2+\ce{Sn^{2+}}

\ceSn2+\ce{Sn^{2+}} can be oxidised to \ceSn4+\ce{Sn^{4+}} (loses 2 more electrons) → acts as a reducing agent

\ceSn2+>Sn4++2e\ce{Sn^{2+} -> Sn^{4+} + 2e-} (reducing)

Step 3: Analyse B4+\text{B}^{4+} = \cePb4+\ce{Pb^{4+}}

\cePb4+\ce{Pb^{4+}} tends to gain electrons to form more stable \cePb2+\ce{Pb^{2+}} → acts as an oxidising agent

\cePb4++2e>Pb2+\ce{Pb^{4+} + 2e- -> Pb^{2+}} (oxidising)

Answer: (c) reducing and oxidising

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