The group 14 elements A and B have the first ionisation enthalpy values of 708 and 715 kJ mol-1 respectively. The above…
p-Block Elements (Class 12) · Class 12 · JEE Main Previous Year Question
The group 14 elements A and B have the first ionisation enthalpy values of 708 and 715 kJ mol respectively. The above values are lowest among their group members. The nature of their ions and respectively is
- a
both reducing
- b
both oxidising
- c✓
reducing and oxidising
- d
oxidising and reducing
reducing and oxidising
Step 1: Identify elements A and B
Group 14 elements: C, Si, Ge, Sn, Pb
First ionisation enthalpies (kJ/mol): C(1086) > Si(786) > Ge(762) > Sn(708) > Pb(715)
The two lowest IE values in Group 14 are Sn (708) and Pb (715).
So: A = Sn (IE = 708), B = Pb (IE = 715)
Step 2: Analyse =
can be oxidised to (loses 2 more electrons) → acts as a reducing agent
(reducing)
Step 3: Analyse =
tends to gain electrons to form more stable → acts as an oxidising agent
(oxidising)
Answer: (c) reducing and oxidising
Practice this question with progress tracking
Want timed practice with adaptive difficulty? Solve this question (and hundreds more from p-Block Elements (Class 12)) inside The Crucible, our adaptive practice platform.
More JEE Main p-Block Elements (Class 12) PYQs
The total number of acidic oxides from the following list is: NO,\ N2O,\ B2O3,\ N2O5,\ CO,\ SO3,\ P4O10
Given below are the oxides: Na2O,\ As2O3,\ N2O,\ NO and Cl2O7 Number of amphoteric oxides is:
Consider the following elements In, Tl, Al, Pb, Sn and Ge. The most stable oxidation states of elements with highest and lowest first ionisation enthalpies, respectively, are:
When a salt is treated with sodium hydroxide solution it gives gas X. On passing gas X through reagent Y a brown coloured precipitate is formed. X and Y respectively, are
The amphoteric oxide among V2O3, V2O4 and V2O5 upon reaction with alkali leads to formation of an oxide anion. The oxidation state of V in the oxide anion is: (a) +3 (b) +7 (c) +5 (d) +4