JEE Main · 2020 · Shift-ImediumPB12-072

The structure of PCl5 in the solid state is:

p-Block Elements (Class 12) · Class 12 · JEE Main Previous Year Question

Question

The structure of PCl5\mathrm{PCl_5} in the solid state is:

Options
  1. a

    tetrahedral [PCl4]+[\mathrm{PCl_4}]^+ and octahedral [PCl6][\mathrm{PCl_6}]^-

  2. b

    square planar [PCl4]+[\mathrm{PCl_4}]^+ and octahedral [PCl6][\mathrm{PCl_6}]^-

  3. c

    square pyramidal

  4. d

    trigonal bipyramidal

Correct Answera

tetrahedral [PCl4]+[\mathrm{PCl_4}]^+ and octahedral [PCl6][\mathrm{PCl_6}]^-

Detailed Solution

Strategy: Relate intermolecular forces and molecular size to the boiling points of noble gases.

Step 1: Dispersion Forces Noble gases consist of single atoms held only by weak London dispersion forces. As atomic size and number of electrons increase from \ceHe\ce{He} to \ceRn\ce{Rn}, the polarizability increases.

Step 2: Boiling Point Trend Stronger dispersion forces result in higher boiling points. Thus, boiling point increases down the group. Matching this trend with the provided values or order gives the answer.

Answer: (Option) [a] [Based on property trend in question]\boxed{\text{Answer: (Option) [a] [Based on property trend in question]}}

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