JEE Main · 2021 · Shift-IeasyPB12-008

Which one of the following group-15 hydride is the strongest reducing agent?

p-Block Elements (Class 12) · Class 12 · JEE Main Previous Year Question

Question

Which one of the following group-15 hydride is the strongest reducing agent?

Options
  1. a

    AsH3\mathrm{AsH_3}

  2. b

    BiH3\mathrm{BiH_3}

  3. c

    PH3\mathrm{PH_3}

  4. d

    SbH3\mathrm{SbH_3}

Correct Answerb

BiH3\mathrm{BiH_3}

Detailed Solution

Strategy: Relate reducing power to the stability of the hydride bond.

Step 1: Bond Length Trend Down Group 15, the size of the element (M)(M) increases, causing the MHM-H bond length to increase and the bond strength to decrease significantly.

Step 2: Reducing Power As the bond dissociation enthalpy decreases, the ability to donate hydrogen increases. \ceBiH3\ce{BiH3} has the weakest bond and is thus the strongest reducing agent.

Answer: (Option) [b] \ceBiH3\boxed{\text{Answer: (Option) [b] $\ce{BiH3}$}}

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