JEE Main · 2024 · Shift-IeasySOL-013

A solution of two miscible liquids showing negative deviation from Raoult's law will have:

Solutions · Class 12 · JEE Main Previous Year Question

Question

A solution of two miscible liquids showing negative deviation from Raoult's law will have:

Options
  1. a

    increased vapour pressure, increased boiling point

  2. b

    increased vapour pressure, decreased boiling point

  3. c

    decreased vapour pressure, decreased boiling point

  4. d

    decreased vapour pressure, increased boiling point

Correct Answerd

decreased vapour pressure, increased boiling point

Detailed Solution

Strategy:\n> Negative deviation means A-B interactions are stronger than pure liquid interactions. This reduces the tendency of molecules to escape into the vapor phase.\n\nAnalysis:\n1. Vapor Pressure: Stronger attractions impliesimplies harder to evaporate impliesimplies decreased vapor pressure.\n2. Boiling Point: A lower vapor pressure means a higher temperature is required to reach atmospheric pressure impliesimplies increased boiling point.\n\ntextAnswer:(4)\boxed{\\text{Answer: (4)}}

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