JEE Main · 2025 · Shift-ImediumATOM-208

According to Bohr's model of hydrogen atom, which of the following statement is incorrect?

Structure of Atom · Class 11 · JEE Main Previous Year Question

Question

According to Bohr's model of hydrogen atom, which of the following statement is incorrect?

Options
  1. a

    Radius of 3rd3^{rd} orbit is nine times larger than that of 1st1^{st} orbit.

  2. b

    Radius of 8th8^{th} orbit is four times larger than that of 4th4^{th} orbit.

  3. c

    Radius of 6th6^{th} orbit is three times larger than that of 4th4^{th} orbit.

  4. d

    Radius of 4th4^{th} orbit is four times larger than that of 2nd2^{nd} orbit.

Correct Answerc

Radius of 6th6^{th} orbit is three times larger than that of 4th4^{th} orbit.

Detailed Solution

🧠 The Radius Rule Bohr's model states that the radius of an electron's orbit increases with the square of the principal quantum number. rnn2r_n \propto n^2 To find an incorrect statement, we just need to verify if the ratios of n2n^2 match the claims made in the options.

🗺️ The Ratio Audit

  • Statement A: r3/r1r_3 / r_1. Ratio =32/12=9= 3^2 / 1^2 = 9. (Correct)
  • Statement B: r8/r4r_8 / r_4. Ratio =82/42=64/16=4= 8^2 / 4^2 = 64 / 16 = 4. (Correct)
  • Statement D: r4/r2r_4 / r_2. Ratio =42/22=16/4=4= 4^2 / 2^2 = 16 / 4 = 4. (Correct)
  • Statement C: r6/r4r_6 / r_4. Ratio =62/42=36/16=2.25= 6^2 / 4^2 = 36 / 16 = 2.25. The statement claims it is "three times larger" (3.03.0). (Incorrect)

The Square Test Always think in terms of squares. 484 \to 8 (2×2\times nn) means 4×4\times radius. 242 \to 4 (2×2\times nn) means 4×4\times radius. 464 \to 6 (1.5×1.5\times nn) means 2.25×2.25\times radius. 33 is not a square of a simple nn ratio here.

⚠️ Linearity Trap Don't fall for the trap of thinking rr is proportional to nn. If rnr \propto n, then r6r_6 would be 1.51.5 times r4r_4. If rn2r \propto n^2, it is 2.252.25 times. The statement "three times" is wrong in both universes!

Answer: (c)\boxed{\text{Answer: (c)}}

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