JEE Main · 2023 · Shift-IeasyATOM-048

The energy of an electron in the first Bohr orbit of hydrogen atom is -2.18 10-18 J. Its energy in the third Bohr orbit…

Structure of Atom · Class 11 · JEE Main Previous Year Question

Question

The energy of an electron in the first Bohr orbit of hydrogen atom is 2.18×1018-2.18 \times 10^{-18} J. Its energy in the third Bohr orbit is ______.

Options
  1. a

    19\frac{1}{9}th of the value

  2. b

    127\frac{1}{27} of this value

  3. c

    Three times of this value

  4. d

    One third of this value

Correct Answera

19\frac{1}{9}th of the value

Detailed Solution

🧠 The Energy Well Inversion In the Bohr model, energy is inversely proportional to the square of the shell number (n2n^2). As you move further from the nucleus, the binding energy drops sharply.

🗺️ The Rydberg Path

  1. Proportionality: En1/n2E_n \propto 1/n^2.
  2. Case: Comparison of Ground state (n=1n=1) and 3rd orbit (n=3n=3).
  3. Calculation: E3=E1×132=E19E_3 = E_1 \times \frac{1}{3^2} = \frac{E_1}{9}

The "Denominator Square" Shortcut If shell number is tripled (131 \to 3), the energy must drop to 1/9th1/9\text{th}. Just look at the integer and square it!

⚠️ Common Traps Picking "one third" (1/3). Linear scaling applies to velocity (v1/nv \propto 1/n); energy is siempre based on the square.

Answer: 1/9th of the value\boxed{\text{Answer: 1/9th of the value}}

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