JEE Main · 2019 · Shift-IImediumATOM-127

Among the following, the energy of 2s orbital is lowest in:

Structure of Atom · Class 11 · JEE Main Previous Year Question

Question

Among the following, the energy of 2s orbital is lowest in:

Options
  1. a

    K

  2. b

    H

  3. c

    Na

  4. d

    Li

Correct Answera

K

Detailed Solution

🧠 The Nuclear Pull The energy of a specific orbital (like 2s2s) depends on how strongly the nucleus "grips" it. More protons (ZZ) = stronger grip = lower (more negative) energy level.

🗺️ Atomic Number Check

  • H: Z=1Z = 1
  • Li: Z=3Z = 3
  • Na: Z=11Z = 11
  • K: Z=19Z = 19 Since Potassium (K) has the highest atomic number, its 2s2s electrons are submerged deeper into the potential well than those of the lighter elements.

The ZZ-Scaling Rule For any common subshell (like 1s1s or 2s2s), the energy becomes more negative as you move down a group. The "floor" of the energy well gets deeper as you add protons.

⚠️ Common Traps Don't confuse "lowest energy" (deepest well) with "lowest principal shell" (highest well). K has the lowest 2s2s energy because it has the strongest positive nucleus in this set.

Answer: (a)\boxed{\text{Answer: (a)}}

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