JEE Main · 2020 · Shift-IIhardATOM-124

Consider the hypothetical situation where the azimuthal quantum number, l, takes values 0, 1, 2, ....... n+1. Where n…

Structure of Atom · Class 11 · JEE Main Previous Year Question

Question

Consider the hypothetical situation where the azimuthal quantum number, l, takes values 0, 1, 2, ....... n+1. Where n is the principal quantum number. Then, the element with atomic number:

Options
  1. a

    9 is the first alkali metal

  2. b

    13 has a half-filled valence subshell

  3. c

    8 is the first noble gas

  4. d

    6 has a 2p-valence subshell

Correct Answerb

13 has a half-filled valence subshell

Detailed Solution

🧠 The Hypothetical Shift Standard quantum rules say l<nl < n. In this universe, ll can go up to n+1n+1. This creates "super-shells" with massive capacity right from the start.

🗺️ The Ground State Fill For n=1n=1: ll can be 0(s),1(p),2(d)0(s), 1(p), 2(d).

  • Slots: 2(1s)+6(1p)+10(1d)=182(1s) + 6(1p) + 10(1d) = 18 electrons.
  • The first "shell" can hold 18 electrons.
  1. First Noble Gas: Atomic number 18 (End of shell).
  2. First Alkali: Atomic number 1 (Start of shell).
  3. Check Atomic Number 13: Fill order for 13 electrons: 1s21p61d51s^2 1p^6 1d^5. The 1d1d subshell has a capacity of 1010. Having 55 electrons means it is exactly half-filled.

The Capacity Scaling In this model, the capacity of shell nn is 2(n+2)282(n+2)^2 - 8? No, just calculate subshells: (1s,1p,1d)=2,6,10(1s, 1p, 1d) = 2, 6, 10. Total 1818. For any element X<18X < 18, they are all in the n=1n=1 shell!

⚠️ Common Traps Don't apply standard periodicity. In this world, 1p1p and 1d1d exist in the very first shell, completely changing the identity of the elements.

Answer: (b)\boxed{\text{Answer: (b)}}

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