JEE Main · 2020 · Shift-IIhardATOM-124

Consider the hypothetical situation where the azimuthal quantum number, l, takes values 0, 1, 2, ....... n+1. Where n…

Structure of Atom · Class 11 · JEE Main Previous Year Question

Question

Consider the hypothetical situation where the azimuthal quantum number, l, takes values 0, 1, 2, ....... n+1. Where n is the principal quantum number. Then, the element with atomic number:

Options
  1. a

    9 is the first alkali metal

  2. b

    13 has a half-filled valence subshell

  3. c

    8 is the first noble gas

  4. d

    6 has a 2p-valence subshell

Correct Answerb

13 has a half-filled valence subshell

Detailed Solution

🧠 The Hypothetical Shift Standard quantum rules say l<nl < n. In this universe, ll can go up to n+1n+1. This creates "super-shells" with massive capacity right from the start.

🗺️ The Ground State Fill For n=1n=1: ll can be 0(s),1(p),2(d)0(s), 1(p), 2(d).

  • Slots: 2(1s)+6(1p)+10(1d)=182(1s) + 6(1p) + 10(1d) = 18 electrons.
  • The first "shell" can hold 18 electrons.
  1. First Noble Gas: Atomic number 18 (End of shell).
  2. First Alkali: Atomic number 1 (Start of shell).
  3. Check Atomic Number 13: Fill order for 13 electrons: 1s21p61d51s^2 1p^6 1d^5. The 1d1d subshell has a capacity of 1010. Having 55 electrons means it is exactly half-filled.

The Capacity Scaling In this model, the capacity of shell nn is 2(n+2)282(n+2)^2 - 8? No, just calculate subshells: (1s,1p,1d)=2,6,10(1s, 1p, 1d) = 2, 6, 10. Total 1818. For any element X<18X < 18, they are all in the n=1n=1 shell!

⚠️ Common Traps Don't apply standard periodicity. In this world, 1p1p and 1d1d exist in the very first shell, completely changing the identity of the elements.

Answer: (b)\boxed{\text{Answer: (b)}}

Practice this question with progress tracking

Want timed practice with adaptive difficulty? Solve this question (and hundreds more from Structure of Atom) inside The Crucible, our adaptive practice platform.

Consider the hypothetical situation where the azimuthal quantum number, l, takes values 0, 1, 2,… (JEE Main 2020) | Canvas Classes