JEE Main · 2019 · Shift-IImediumATOM-044

The 71st electron of an element X with an atomic number of 71 enters the orbital:

Structure of Atom · Class 11 · JEE Main Previous Year Question

Question

The 71st71^{\text{st}} electron of an element X with an atomic number of 71 enters the orbital:

Options
  1. a

    5d

  2. b

    4f

  3. c

    6p

  4. d

    6s

Correct Answera

5d

Detailed Solution

🧠 The f-block Finale The element with Z=71Z=71 is Lutetium (\ceLu\ce{Lu}). It marks the very last spot in the lanthanoid series. We need to determine exactly where that final 71st electron "lands" during the building process.

🗺️ The Aufbau Ladder

  1. Noble Gas: Xenon (Z=54Z=54).
  2. Filling Period 6:
    • 6s26s^2: electrons 55 and 56.
    • 4f144f^{14}: electrons 57 through 70. (The f-subshell is fully filled here!)
  3. The Next Room: With 4f4f full, the 71st electron must now enter the 5d subshell. Result: Electron 71 is in the 5d5d orbital.

The Periodic Anchor Look at the Periodic Table row. Lutetium (Z=71Z=71) is often grouped under the "d-block" because it has a partially filled 5d5d orbital. If you remember that the lanthanoids end at Z=71Z=71 with a "d" electron, this question is a 5-second check.

⚠️ Common Traps Many assume that since Lutetium is a Lanthanoid, the last electron must be in 4f4f. This is incorrect! The 4f4f subshell is completed with the 70th electron (\ceYb\ce{Yb}). Think of \ceLu\ce{Lu} as the "bridge" back to the d-block.

Answer: (a)\boxed{\text{Answer: (a)}}

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