JEE Main · 2024 · Shift-ImediumATOM-040

The electronic configuration for Neodymium is: [Atomic Number for Neodymium = 60]

Structure of Atom · Class 11 · JEE Main Previous Year Question

Question

The electronic configuration for Neodymium is:

[Atomic Number for Neodymium = 60]

Options
  1. a

    [Xe]4f46s2[\text{Xe}]\,4f^4\,6s^2

  2. b

    [Xe]5f47s2[\text{Xe}]\,5f^4\,7s^2

  3. c

    [Xe]4f66s2[\text{Xe}]\,4f^6\,6s^2

  4. d

    [Xe]4f15d16s2[\text{Xe}]\,4f^1\,5d^1\,6s^2

Correct Answera

[Xe]4f46s2[\text{Xe}]\,4f^4\,6s^2

Detailed Solution

🧠 Navigating the f-block Jungle Neodymium lives in the Lanthanoid series (Period 6). For these elements, the filling order follows the 6s4f5d6s \to 4f \to 5d route. Key to Z=60 is working forward from the Xenon (Z=54Z=54) baseline.

🗺️ The Lanthanoid Launch

  1. Baseline: Xenon (Z=54Z=54).
  2. Next Steps: Z=6054=6Z = 60 - 54 = 6 electrons to place.
  3. The 6s Buffer: The 6s6s orbital is always filled first with 2 electrons. Remaining =4= 4.
  4. Entering the 4f House: For early lanthanoids (like Nd), there is usually 00 electrons in 5d5d. So all 44 remaining electrons enter the 4f4f subshell. Result: [Xe]4f46s2[\text{Xe}] 4f^4 6s^2.

The f-block Offset A useful rule of thumb: For lanthanoids (Z=57Z=57 to 7171), the number of electrons in the 4f4f subshell is often (Z56)(Z - 56). For Nd (Z=60Z=60): 6056=460 - 56 = 4. So, 4f44f^4. (Note: Exceptions like Gd exist, but this works for Nd!)

⚠️ Common Traps Don't jump to option (4) [Xe]4f15d16s2[\text{Xe}] 4f^1 5d^1 6s^2. Only Lanthanum (Z=57Z=57) and Gadolinium (Z=64Z=64) store a single electron in 5d5d for specific stability reasons. Neodymium follows the standard direct 4f4f filling.

Answer: (a)\boxed{\text{Answer: (a)}}

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