JEE Main · 2020 · Shift-IImediumATOM-034

The number of subshells associated with n = 4 and m = -2 quantum numbers is:

Structure of Atom · Class 11 · JEE Main Previous Year Question

Question

The number of subshells associated with n=4n = 4 and m=2m = -2 quantum numbers is:

Options
  1. a

    8

  2. b

    2

  3. c

    16

  4. d

    4

Correct Answerb

2

Detailed Solution

🧠 The Quantum Address Filter We need to identify which subshells (ll) in shell n=4n=4 are capable of containing an orbital with the orientation m=2m=-2.

🗺️ The Value Audit

  1. Principal (n=4n=4): Allowed ll are 0(s), 1(p), 2(d), 3(f).
  2. Magnetic (m=2m=-2): For a magnetic number to exist, the condition is lml \geq |m|.
  3. Filtering:
    • l=0,1l=0, 1: m|m| limit is too low (mm cannot reach 2).
    • l=2(d)l=2 (d): m{2,1,0,1,2}m \in \{-2, -1, 0, 1, 2\}. (Match!)
    • l=3(f)l=3 (f): m{3,2,1,0,1,2,3}m \in \{-3, -2, -1, 0, 1, 2, 3\}. (Match!) The subshells are 4d and 4f.

The "|m| Boundary" Shortcut A subshell houses an orbital mm if ll is at least m|m|. Since 2=2|-2|=2, only l=2l=2 and l=3l=3 subshells in the 4th shell contain it. Total = 2.

⚠️ Common Traps Mistaking "subshells" for "orbitals." While there are 2 subshells, there are many more orbitals in total. The question specifically asks for the sub-level count.

Answer: 2\boxed{\text{Answer: 2}}

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