JEE Main · 2025 · Shift-IImediumBOND-186

Given below are two statements: Statement I: H2Se is more acidic than H2Te. Statement II: H2Se has higher bond enthalpy…

Chemical Bonding · Class 11 · JEE Main Previous Year Question

Question

Given below are two statements:

Statement I: \ceH2Se\ce{H2Se} is more acidic than \ceH2Te\ce{H2Te}.

Statement II: \ceH2Se\ce{H2Se} has higher bond enthalpy for dissociation than \ceH2Te\ce{H2Te}.

In the light of the above statements, choose the correct answer from the options given below:

Options
  1. a

    Both statement I and Statement II are false.

  2. b

    Both statement I and Statement II are true.

  3. c

    Statement I is true but Statement II is false.

  4. d

    Statement I is false but Statement II is true.

Correct Answerd

Statement I is false but Statement II is true.

Detailed Solution

🧠 Acidity of group 16 hydrides increases down the group because bond dissociation enthalpy decreases (weaker bond → easier H⁺ release). Electronegativity of S and Se are both relatively low so that's not the driving factor.

🗺️ Statement I — \ceH2Se\ce{H2Se} is more acidic than \ceH2Te\ce{H2Te}:

Acidity order (group 16): \ceH2O<\ceH2S<\ceH2Se<\ceH2Te\ce{H2O} < \ce{H2S} < \ce{H2Se} < \ce{H2Te}

\ceH2Te\ce{H2Te} is MORE acidic than \ceH2Se\ce{H2Se} (not the other way around).

Statement I is FALSE

Statement II — \ceH2Se\ce{H2Se} has higher bond enthalpy than \ceH2Te\ce{H2Te}:

Bond dissociation enthalpy decreases down the group (larger atom, poorer orbital overlap):

H–O>H–S>H–Se>H–Te\text{H–O} > \text{H–S} > \text{H–Se} > \text{H–Te}

So \ceH2Se\ce{H2Se} has higher Se–H bond enthalpy than Te–H bond enthalpy in \ceH2Te\ce{H2Te}.

Statement II is TRUE

Answer: Statement I is false but Statement II is true\boxed{\text{Answer: Statement I is false but Statement II is true}}

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