Given below are two statements: Statement I: H2Se is more acidic than H2Te. Statement II: H2Se has higher bond enthalpy…
Chemical Bonding · Class 11 · JEE Main Previous Year Question
Given below are two statements:
Statement I: is more acidic than .
Statement II: has higher bond enthalpy for dissociation than .
In the light of the above statements, choose the correct answer from the options given below:
- a
Both statement I and Statement II are false.
- b
Both statement I and Statement II are true.
- c
Statement I is true but Statement II is false.
- d✓
Statement I is false but Statement II is true.
Statement I is false but Statement II is true.
🧠 Acidity of group 16 hydrides increases down the group because bond dissociation enthalpy decreases (weaker bond → easier H⁺ release). Electronegativity of S and Se are both relatively low so that's not the driving factor.
🗺️ Statement I — is more acidic than :
Acidity order (group 16):
is MORE acidic than (not the other way around).
Statement I is FALSE ✗
Statement II — has higher bond enthalpy than :
Bond dissociation enthalpy decreases down the group (larger atom, poorer orbital overlap):
So has higher Se–H bond enthalpy than Te–H bond enthalpy in .
Statement II is TRUE ✓
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