JEE Main · 2020 · Shift-ImediumBOND-117

Of the species NO, NO+, NO2+ and NO-, the one with minimum bond strength is:

Chemical Bonding · Class 11 · JEE Main Previous Year Question

Question

Of the species NO, NO+\mathrm{NO^+}, NO2+\mathrm{NO^{2+}} and NO\mathrm{NO^-}, the one with minimum bond strength is:

Options
  1. a

    NO+\mathrm{NO^+}

  2. b

    NO

  3. c

    NO2+\mathrm{NO^{2+}}

  4. d

    NO\mathrm{NO^-}

Correct Answerd

NO\mathrm{NO^-}

Detailed Solution

🧠 Bond strength ∝ bond order. Calculate BO for each species by counting total electrons (N = 7e, O = 8e).

| Species | Electrons | BO | |---|---|---| | \ceNO2+\ce{NO^{2+}} | 13 | (10−3)/2 = 3.5 (strongest) | | \ceNO+\ce{NO+} | 14 | (10−4)/2 = 3 | | NO | 15 | (10−5)/2 = 2.5 | | \ceNO\ce{NO-} | 16 | (10−6)/2 = 2 (weakest) |

Each additional electron from \ceNO2+\ce{NO^{2+}} goes into an antibonding π\pi^* orbital, progressively weakening the bond. \ceNO\ce{NO-} has the lowest BO and thus the minimum bond strength.

Answer: (d) \ceNO\boxed{\text{Answer: (d) } \ce{NO-}}

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