JEE Main · 2025 · Shift-IhardBOND-174

A molecule with the formula AX4Y has all its elements from p-block. Element A is rarest, monoatomic, non-radioactive…

Chemical Bonding · Class 11 · JEE Main Previous Year Question

Question

A molecule with the formula \ceAX4Y\ce{AX4Y} has all its elements from p-block. Element A is rarest, monoatomic, non-radioactive from its group and has the lowest ionization enthalpy value among A, X and Y. Elements X and Y have first and second highest electronegativity values respectively among all the known elements. The shape of the molecule is:

Options
  1. a

    Square pyramidal

  2. b

    Octahedral

  3. c

    Pentagonal planar

  4. d

    Trigonal bipyramidal

Correct Answera

Square pyramidal

Detailed Solution

🧠 Identify elements A, X, Y from the clues, then determine the molecular geometry of AX₄Y.

🗺️ Step 1 — Identify X and Y:

  • X has the highest electronegativity among all elements → F (EN = 3.98)
  • Y has the second highest electronegativityO (EN = 3.44)

Step 2 — Identify A:

A is from p-block, rarest in its group, monoatomic (noble gas), non-radioactive, and has the lowest IE among A, F, O:

  • Rarest non-radioactive noble gas: Xe (Z = 54)
  • IE of Xe ≈ 1170 kJ/mol; IE of F ≈ 1681; IE of O ≈ 1314 → Xe has lowest IE ✓

Step 3 — Molecule is XeF4O\mathrm{XeF_4O}XeOF4\mathrm{XeOF_4}

Xe has: 4 Xe–F bonds + 1 Xe=O bond + 1 lone pair on Xe Steric number = 4 + 1 + 1 = 6 → sp³d² hybridization

Electron geometry: octahedral The lone pair occupies an equatorial-like position (or axial) → lone pair + 1 oxygen (double bond) + 4 F (single bonds) → square pyramidal geometry (Xe at center, 4 F at base, O at apex)

Answer: Square pyramidal\boxed{\text{Answer: Square pyramidal}}

Practice this question with progress tracking

Want timed practice with adaptive difficulty? Solve this question (and hundreds more from Chemical Bonding) inside The Crucible, our adaptive practice platform.

A molecule with the formula AX4Y has all its elements from p-block. Element A is rarest,… (JEE Main 2025) | Canvas Classes