A molecule with the formula AX4Y has all its elements from p-block. Element A is rarest, monoatomic, non-radioactive…
Chemical Bonding · Class 11 · JEE Main Previous Year Question
A molecule with the formula has all its elements from p-block. Element A is rarest, monoatomic, non-radioactive from its group and has the lowest ionization enthalpy value among A, X and Y. Elements X and Y have first and second highest electronegativity values respectively among all the known elements. The shape of the molecule is:
- a✓
Square pyramidal
- b
Octahedral
- c
Pentagonal planar
- d
Trigonal bipyramidal
Square pyramidal
🧠 Identify elements A, X, Y from the clues, then determine the molecular geometry of AX₄Y.
🗺️ Step 1 — Identify X and Y:
- X has the highest electronegativity among all elements → F (EN = 3.98)
- Y has the second highest electronegativity → O (EN = 3.44)
Step 2 — Identify A:
A is from p-block, rarest in its group, monoatomic (noble gas), non-radioactive, and has the lowest IE among A, F, O:
- Rarest non-radioactive noble gas: Xe (Z = 54)
- IE of Xe ≈ 1170 kJ/mol; IE of F ≈ 1681; IE of O ≈ 1314 → Xe has lowest IE ✓
Step 3 — Molecule is →
Xe has: 4 Xe–F bonds + 1 Xe=O bond + 1 lone pair on Xe Steric number = 4 + 1 + 1 = 6 → sp³d² hybridization
Electron geometry: octahedral The lone pair occupies an equatorial-like position (or axial) → lone pair + 1 oxygen (double bond) + 4 F (single bonds) → square pyramidal geometry (Xe at center, 4 F at base, O at apex)
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