The correct order of increasing intermolecular hydrogen bond strength is
Chemical Bonding · Class 11 · JEE Main Previous Year Question
The correct order of increasing intermolecular hydrogen bond strength is
- a✓
- b
- c
- d
🧠 H-bond strength depends on the electronegativity of the atom bonded to H and the polarity of the X–H bond (donor strength).
🗺️ Analyse each molecule:
- HCN (): H is bonded to C (low electronegativity, poor H-bond donor); only weak interaction possible → weakest ✗
- : H bonded to O; O is highly electronegative → strong O–H···O H-bond; O also has 2 lone pairs as acceptors
- : H bonded to N; N is electronegative; N has a concentrated lone pair → forms N–H···N H-bonds
⚠️ forms no H-bonds at all (H bonded to C, which is non-electronegative).
Increasing H-bond strength:
⚡ Among these three, HCN is the weakest donor (C–H bond). Between and , while O is more electronegative, the lone pair on N in is more available and directional, contributing to stronger effective H-bonding in this comparison.
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