The element that shows greater ability to form p-p multiple bonds is:
Chemical Bonding · Class 11 · JEE Main Previous Year Question
The element that shows greater ability to form multiple bonds is:
- a
Sn
- b✓
C
- c
Si
- d
Ge
C
🧠 – bonding (side-by-side overlap of p orbitals to form π bonds) is strongest when the atoms are small and have compact 2p orbitals that can overlap effectively. As the atomic radius increases down a group, p orbital overlap decreases.
- C (Period 2): small size, compact 2p orbitals → strong – bonds → forms C=C, C=O, C≡N routinely ✓
- Si (Period 3): larger atomic radius → 3p orbitals more diffuse → poor – overlap → Si prefers single bonds
- Ge, Sn: even larger → essentially no stable – bonds
⚠️ This is why is a covalent network solid (Si–O single bonds) while is a gas with O=C=O double bonds.
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