JEE Main · 2019 · Shift-IIeasyBOND-049

The element that shows greater ability to form p-p multiple bonds is:

Chemical Bonding · Class 11 · JEE Main Previous Year Question

Question

The element that shows greater ability to form pπpπ\mathrm{p\pi-p\pi} multiple bonds is:

Options
  1. a

    Sn

  2. b

    C

  3. c

    Si

  4. d

    Ge

Correct Answerb

C

Detailed Solution

🧠 pπ\text{p}\pipπ\text{p}\pi bonding (side-by-side overlap of p orbitals to form π bonds) is strongest when the atoms are small and have compact 2p orbitals that can overlap effectively. As the atomic radius increases down a group, p orbital overlap decreases.

  • C (Period 2): small size, compact 2p orbitals → strong pπ\text{p}\pipπ\text{p}\pi bonds → forms C=C, C=O, C≡N routinely ✓
  • Si (Period 3): larger atomic radius → 3p orbitals more diffuse → poor pπ\text{p}\pipπ\text{p}\pi overlap → Si prefers single bonds
  • Ge, Sn: even larger → essentially no stable pπ\text{p}\pipπ\text{p}\pi bonds

⚠️ This is why \ceSiO2\ce{SiO2} is a covalent network solid (Si–O single bonds) while \ceCO2\ce{CO2} is a gas with O=C=O double bonds.

Answer: (b) C\boxed{\text{Answer: (b) C}}

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