JEE Main · 2022 · Shift-IhardCEQ-028

For a reaction at equilibrium A(g) B(g) + 12C(g), the relation between dissociation constant (K), degree of…

Chemical Equilibrium · Class 11 · JEE Main Previous Year Question

Question

For a reaction at equilibrium A(g)B(g)+12C(g)\mathrm{A(g) \rightleftharpoons B(g) + \frac{1}{2}C(g)}, the relation between dissociation constant (KK), degree of dissociation (α\alpha) and equilibrium pressure (pp) is given by:

Options
  1. a

    K=α3/2p1/2(2+α)1/2(1α)K = \frac{\alpha^{3/2} p^{1/2}}{(2+\alpha)^{1/2}(1-\alpha)}

  2. b

    K=α1/2p3/2(1+32α)1/2(1α)K = \frac{\alpha^{1/2} p^{3/2}}{(1+\frac{3}{2}\alpha)^{1/2}(1-\alpha)}

  3. c

    K=(αp)3/2(1+32α)1/2(1α)K = \frac{(\alpha p)^{3/2}}{(1+\frac{3}{2}\alpha)^{1/2}(1-\alpha)}

  4. d

    K=(αp)3/2(1+α)(1α)1/2K = \frac{(\alpha p)^{3/2}}{(1+\alpha)(1-\alpha)^{1/2}}

Correct Answera

K=α3/2p1/2(2+α)1/2(1α)K = \frac{\alpha^{3/2} p^{1/2}}{(2+\alpha)^{1/2}(1-\alpha)}

Detailed Solution

Step 1 — ICE table (start with 1 mol A):

| | A | B | C | Total | |--|--|--|--|--| | Initial | 1 | 0 | 0 | 1 | | Equil. | 1α1-\alpha | α\alpha | α/2\alpha/2 | 1+α/21+\alpha/2 |

Note: 1+α/2=(2+α)/21 + \alpha/2 = (2+\alpha)/2

Step 2 — Partial pressures: PA=(1α)p(2+α)/2=2(1α)p2+αPB=2αp2+α,PC=αp2+αP_A = \frac{(1-\alpha)p}{(2+\alpha)/2} = \frac{2(1-\alpha)p}{2+\alpha} P_B = \frac{2\alpha p}{2+\alpha}, \quad P_C = \frac{\alpha p}{2+\alpha}

Step 3 — KpK_p: K=PBPC1/2PA=2αp2+α(αp2+α)1/22(1α)p2+α=αα1/2p1/2(1α)(2+α)1/2=α3/2p1/2(1α)(2+α)1/2K = \frac{P_B \cdot P_C^{1/2}}{P_A} = \frac{\frac{2\alpha p}{2+\alpha} \cdot \left(\frac{\alpha p}{2+\alpha}\right)^{1/2}}{\frac{2(1-\alpha)p}{2+\alpha}} = \frac{\alpha \cdot \alpha^{1/2} \cdot p^{1/2}}{(1-\alpha)(2+\alpha)^{1/2}} = \frac{\alpha^{3/2} p^{1/2}}{(1-\alpha)(2+\alpha)^{1/2}}

Answer: Option (1)

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