JEE Main · 2020 · Shift-IIeasyCEQ-007

If the equilibrium constant for A B + C is Keq(1) and that of B + C P is Keq(2), the equilibrium constant for A P is:

Chemical Equilibrium · Class 11 · JEE Main Previous Year Question

Question

If the equilibrium constant for AB+C\mathrm{A \rightleftharpoons B + C} is Keq(1)K_{eq}^{(1)} and that of B+CP\mathrm{B + C \rightleftharpoons P} is Keq(2)K_{eq}^{(2)}, the equilibrium constant for AP\mathrm{A \rightleftharpoons P} is:

Options
  1. a

    Keq(1)/Keq(2)K_{eq}^{(1)} / K_{eq}^{(2)}

  2. b

    Keq(2)Keq(1)K_{eq}^{(2)} - K_{eq}^{(1)}

  3. c

    Keq(1)+Keq(2)K_{eq}^{(1)} + K_{eq}^{(2)}

  4. d

    Keq(1)Keq(2)K_{eq}^{(1)} \cdot K_{eq}^{(2)}

Correct Answerd

Keq(1)Keq(2)K_{eq}^{(1)} \cdot K_{eq}^{(2)}

Detailed Solution

Rule: When reactions are added, their equilibrium constants are multiplied.

Step 1 — Add the two reactions: AB+CKeq(1)B+CPKeq(2)\mathrm{A \rightleftharpoons B + C} \quad K_{eq}^{(1)} \mathrm{B + C \rightleftharpoons P} \quad K_{eq}^{(2)}

Adding: AP\mathrm{A \rightleftharpoons P}

Step 2 — Combined equilibrium constant: K=Keq(1)×Keq(2)K = K_{eq}^{(1)} \times K_{eq}^{(2)}

This follows from the fact that K=[P][A]K = \frac{[P]}{[A]} and: Keq(1)×Keq(2)=[B][C][A]×[P][B][C]=[P][A]K_{eq}^{(1)} \times K_{eq}^{(2)} = \frac{[B][C]}{[A]} \times \frac{[P]}{[B][C]} = \frac{[P]}{[A]}

Answer: Option (4) — Keq(1)Keq(2)K_{eq}^{(1)} \cdot K_{eq}^{(2)}

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