For elements B, C, N, Li, Be, O and F, the correct order of first ionisation enthalpy is:
Classification of Elements & Periodicity · Class 11 · JEE Main Previous Year Question
For elements B, C, N, Li, Be, O and F, the correct order of first ionisation enthalpy is:
- a
Li < Be < B < C < O < N < F
- b
B < Li < Be < C < N < O < F
- c
Li < Be < B < C < N < O < F
- d✓
Li < B < Be < C < O < N < F
Li < B < Be < C < O < N < F
🧠 Two anomalies in Period 2: Be > B and N > O Across a period, IE normally increases. But two pairs break this rule: Be beats B (filled 2s is more stable than half-filled 2p), and N beats O (half-filled 2p is more stable than paired 2p).
🗺️ Build the order step by step
Normal trend: .
Apply anomaly 1: swap Be and B →
Apply anomaly 2: swap N and O → .
Final order: .
⚠️ Common mistake
Many students only remember one anomaly and miss the other. There are TWO swaps in Period 2: the Be-B swap and the N-O swap. Forget either one and you pick the wrong option.
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