JEE Main · 2023 · Shift-ImediumPERI-025

For elements B, C, N, Li, Be, O and F, the correct order of first ionisation enthalpy is:

Classification of Elements & Periodicity · Class 11 · JEE Main Previous Year Question

Question

For elements B, C, N, Li, Be, O and F, the correct order of first ionisation enthalpy is:

Options
  1. a

    Li < Be < B < C < O < N < F

  2. b

    B < Li < Be < C < N < O < F

  3. c

    Li < Be < B < C < N < O < F

  4. d

    Li < B < Be < C < O < N < F

Correct Answerd

Li < B < Be < C < O < N < F

Detailed Solution

🧠 Two anomalies in Period 2: Be > B and N > O Across a period, IE normally increases. But two pairs break this rule: Be beats B (filled 2s is more stable than half-filled 2p), and N beats O (half-filled 2p is more stable than paired 2p).

🗺️ Build the order step by step Normal trend: \ceLi<\ceBe<\ceB<\ceC<\ceN<\ceO<\ceF\ce{Li} < \ce{Be} < \ce{B} < \ce{C} < \ce{N} < \ce{O} < \ce{F}. Apply anomaly 1: swap Be and B → \ceLi<\ceB<\ceBe<\ceC<...\ce{Li} < \ce{B} < \ce{Be} < \ce{C} < ... Apply anomaly 2: swap N and O → ...<\ceC<\ceO<\ceN<\ceF... < \ce{C} < \ce{O} < \ce{N} < \ce{F}. Final order: \ceLi<\ceB<\ceBe<\ceC<\ceO<\ceN<\ceF\ce{Li} < \ce{B} < \ce{Be} < \ce{C} < \ce{O} < \ce{N} < \ce{F}. image ⚠️ Common mistake Many students only remember one anomaly and miss the other. There are TWO swaps in Period 2: the Be-B swap and the N-O swap. Forget either one and you pick the wrong option.

Answer: (d)\boxed{\text{Answer: (d)}}

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For elements B, C, N, Li, Be, O and F, the correct order of first ionisation enthalpy is: (JEE Main 2023) | Canvas Classes