In comparison to boron, beryllium has:
Classification of Elements & Periodicity · Class 11 · JEE Main Previous Year Question
In comparison to boron, beryllium has:
- a
greater nuclear charge and lesser first ionisation enthalpy
- b✓
lesser nuclear charge and greater first ionisation enthalpy
- c
lesser nuclear charge and lesser first ionisation enthalpy
- d
greater nuclear charge and greater first ionisation enthalpy
lesser nuclear charge and greater first ionisation enthalpy
🧠 Be has FEWER protons than B but HIGHER — that's the famous Be-B anomaly Two facts to compare:
- Nuclear charge: Be has , B has . So Be has fewer protons.
- First ionization enthalpy: Be () has filled , very stable. B has with a lone electron, easy to remove.
Even though Be has lower Z, its filled subshell makes its outer electron harder to pull. So Be has higher than B — despite fewer protons.
🗺️ Match against options , . Be > B in IE. .
So Be has lesser nuclear charge AND greater compared to B.
That is option (b).
⚠️ The trap Option (d) "greater nuclear charge and greater " combines two right-sounding ideas: "Be has higher than B" (true) and the assumption "more protons = higher IE" (often true, but not always). In Be vs B, the LOWER nuclear charge member wins on because of the stable subshell. Always check the nuclear-charge comparison directly — never assume it follows the IE comparison.
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