JEE Main · 2019 · Shift-IIeasyPERI-093

In comparison to boron, beryllium has:

Classification of Elements & Periodicity · Class 11 · JEE Main Previous Year Question

Question

In comparison to boron, beryllium has:

Options
  1. a

    greater nuclear charge and lesser first ionisation enthalpy

  2. b

    lesser nuclear charge and greater first ionisation enthalpy

  3. c

    lesser nuclear charge and lesser first ionisation enthalpy

  4. d

    greater nuclear charge and greater first ionisation enthalpy

Correct Answerb

lesser nuclear charge and greater first ionisation enthalpy

Detailed Solution

🧠 Be has FEWER protons than B but HIGHER IE1IE_1 — that's the famous Be-B anomaly Two facts to compare:

  1. Nuclear charge: Be has Z=4Z = 4, B has Z=5Z = 5. So Be has fewer protons.
  2. First ionization enthalpy: Be (1s22s21s^2\,2s^2) has filled 2s2s, very stable. B has 1s22s22p11s^2\,2s^2\,2p^1 with a lone 2p2p electron, easy to remove.

Even though Be has lower Z, its filled 2s22s^2 subshell makes its outer electron harder to pull. So Be has higher IE1IE_1 than B — despite fewer protons.

🗺️ Match against options IE1(\ceBe)=899IE_1(\ce{Be}) = 899, IE1(\ceB)=801IE_1(\ce{B}) = 801. Be > B in IE. Z(\ceBe)=4<Z(\ceB)=5Z(\ce{Be}) = 4 < Z(\ce{B}) = 5.

So Be has lesser nuclear charge AND greater IE1IE_1 compared to B.

That is option (b).

⚠️ The trap Option (d) "greater nuclear charge and greater IE1IE_1" combines two right-sounding ideas: "Be has higher IE1IE_1 than B" (true) and the assumption "more protons = higher IE" (often true, but not always). In Be vs B, the LOWER nuclear charge member wins on IE1IE_1 because of the stable 2s22s^2 subshell. Always check the nuclear-charge comparison directly — never assume it follows the IE comparison.

Answer: (b)\boxed{\text{Answer: (b)}}

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