JEE Main · 2019 · Shift-IeasyPERI-094

In general, the properties that decrease and increase down a group in the periodic table, respectively, are:

Classification of Elements & Periodicity · Class 11 · JEE Main Previous Year Question

Question

In general, the properties that decrease and increase down a group in the periodic table, respectively, are:

Options
  1. a

    Atomic radius and electronegativity

  2. b

    Electronegativity and atomic radius

  3. c

    Electronegativity and electron gain enthalpy

  4. d

    Electron gain enthalpy and electronegativity

Correct Answerb

Electronegativity and atomic radius

Detailed Solution

🧠 Down a group: atomic radius INCREASES (extra shells); electronegativity DECREASES (electrons farther from nucleus) The question wants two properties — one that decreases down a group, and one that increases. The first slot is the decreasing property; the second slot is the increasing one.

🗺️ Check each property's trend down a group Atomic radius: each new period adds a shell → radius increases down. ↑ Electronegativity: bigger atom holds bonded electrons less tightly → decreases down. ↓ Electron gain enthalpy: usually decreases in magnitude down (with halogen anomalies) → not strictly increasing. Mostly decreasing.

Match options: (a) atomic radius (decreases — wrong), electronegativity (increases — wrong). ✗ (b) electronegativity (decreases ✓), atomic radius (increases ✓). ✓ (c) electronegativity (decreases ✓), electron gain enthalpy (decreases — should be increases). ✗ (d) electron gain enthalpy (decreases ✓), electronegativity (decreases — should be increases). ✗

So option (b) is the only consistent pair.

⚠️ The trap Option (a) flips the order — atomic radius is in the "decreases" slot but it actually INCREASES down a group. Read the slot order: "properties that decrease and increase down a group, respectively". The first listed property must decrease, the second must increase. Atomic radius can never go in the "decreases" slot.

Answer: (b)\boxed{\text{Answer: (b)}}

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