JEE Main · 2022 · Shift-IImediumPERI-066

Metals generally melt at very high temperatures. Among the following which one has the highest melting point?

Classification of Elements & Periodicity · Class 11 · JEE Main Previous Year Question

Question

Metals generally melt at very high temperatures. Among the following which one has the highest melting point?

Options
  1. a

    Ga

  2. b

    Ag

  3. c

    Hg

  4. d

    Cs

Correct Answerb

Ag

Detailed Solution

🧠 Transition metals form strong metallic lattices — Ag's many delocalized electrons hold it together up to nearly 1000 °C Metallic bond strength depends on the number of delocalized valence electrons and how tightly the lattice packs them. Transition metals with d-electron involvement (like Ag) make very strong metallic lattices — high MP. The other three options are notorious low-MP outliers.

🗺️ Compare melting points Ga: 30°C\approx 30\,°\text{C} — melts in your hand. Hg: 39°C\approx -39\,°\text{C} — liquid at room temperature. Cs: 28.5°C\approx 28.5\,°\text{C} — alkali metal with weak metallic bonding. Ag: 962°C\approx 962\,°\text{C} — typical strong-bonded transition metal.

Ag is the only one above 100°C100\,°\text{C}. Easily the highest MP.

⚠️ The trap Students sometimes pick Hg "because it is heavy and dense, must be high MP". Mass and density don't decide MP — bond strength does. Hg's almost-filled 5d106s25d^{10}\,6s^2 shell makes its outer electrons hesitate to delocalize, so the metallic bond is weak. Mass matters for density, not for metallic bond strength.

Answer: (b)\boxed{\text{Answer: (b)}}

Practice this question with progress tracking

Want timed practice with adaptive difficulty? Solve this question (and hundreds more from Classification of Elements & Periodicity) inside The Crucible, our adaptive practice platform.

Metals generally melt at very high temperatures. Among the following which one has the highest… (JEE Main 2022) | Canvas Classes