JEE Main · 2025 · Shift-IImediumPERI-140

The type of oxide formed by the element among Li, Na, Be, Mg, B and Al that has the least atomic radius is:

Classification of Elements & Periodicity · Class 11 · JEE Main Previous Year Question

Question

The type of oxide formed by the element among Li, Na, Be, Mg, B and Al that has the least atomic radius is:

Options
  1. a

    A2O3\text{A}_2\text{O}_3

  2. b

    AO2\text{AO}_2

  3. c

    AO\text{AO}

  4. d

    A2O\text{A}_2\text{O}

Correct Answera

A2O3\text{A}_2\text{O}_3

Detailed Solution

🧠 Smallest atomic radius among Li, Na, Be, Mg, B, Al → Boron. Boron's oxide is \ceB2O3\ce{B2O3}, of type A2O3\text{A}_2\text{O}_3 You first need to identify which element has the smallest radius, then write its oxide formula.

🗺️ Step 1 — find the smallest atom Period 2 atoms (Li, Be, B) are smaller than Period 3 atoms (Na, Mg, Al). So eliminate Na, Mg, Al. Within Period 2: radius decreases left-to-right. Li (152152 pm) > Be (112112 pm) > B (8888 pm). So Boron has the smallest radius.

Step 2 — Boron's oxide B is in Group 13 with valency 3. With oxygen (valency 2), criss-cross to get \ceB2O3\ce{B2O3}. Type: A2O3\text{A}_2\text{O}_3.

⚠️ Common mistake Some students pick option (d) A2O\text{A}_2\text{O} thinking the smallest atom must be Lithium (since Li is at the very top of Group 1). But B sits to the right of Li in Period 2, with three more protons — so B's atom is smaller, not Li's. Always check both period AND group when comparing atomic radii across non-adjacent elements.

Answer: (a)\boxed{\text{Answer: (a)}}

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