JEE Main · 2023 · Shift-IImediumPERI-051

Which one of the following elements will remain as liquid inside pure boiling water?

Classification of Elements & Periodicity · Class 11 · JEE Main Previous Year Question

Question

Which one of the following elements will remain as liquid inside pure boiling water?

Options
  1. a

    Ga

  2. b

    Br

  3. c

    Li

  4. d

    Cs

Correct Answera

Ga

Detailed Solution

🧠 For an element to stay liquid in boiling water, it needs MP below 100 °C, BP above 100 °C, AND no reaction with water Boiling water is at 100°C100\,°\text{C}. So you need a melting point below that (so it is melted) AND a boiling point above that (so it has not vaporized) AND chemical inertness towards water (otherwise it dissolves or reacts).

🗺️ Eliminate each option Br: BP =59°C= 59\,°\text{C}. At 100 °C it would already be vapor, not liquid. Reject. Li: MP =180°C= 180\,°\text{C} — still solid at 100 °C. Plus Li reacts vigorously with water. Reject. Cs: MP =28.5°C= 28.5\,°\text{C} — but Cs explodes on contact with water. Reject. Ga: MP 30°C\approx 30\,°\text{C}, BP 2204°C\approx 2204\,°\text{C}, and Ga does not react with water under normal conditions. Inside boiling water, Ga is a calm shiny liquid pool.

⚠️ The trap Cs looks tempting because of its low melting point (28.5°C28.5\,°\text{C}). But Cs is the most reactive alkali metal — it would never sit calmly in water. The "doesn't react" condition is just as important as the melting point. Ga is the famous safe-with-water low-MP metal.

Answer: (a)\boxed{\text{Answer: (a)}}

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