The correct order of electron gain enthalpy is:
Classification of Elements & Periodicity · Class 11 · JEE Main Previous Year Question
The correct order of electron gain enthalpy is:
- a
- b
- c✓
- d
🧠 S beats O for electron gain — O's orbital is too small, the new electron faces too much repulsion Same story as F vs Cl in halogens. The Period 2 element of any group that gains electrons (O, F) is unusually CRAMPED. Adding an extra electron to a tiny shell raises repulsion. The Period 3 cousin (S, Cl) wins for electron gain enthalpy.
🗺️ Compare Group 16 values (kJ/mol) — most exothermic in this set. . . — anomalously LOW because of repulsion.
Order by magnitude (most to least): S > Se > Te > O.
⚠️ The trap Option (b) puts O at the top: . This is the "expected" group trend without applying the Period 2 anomaly. The smaller atom should win, students think — but for O, the smallness causes too much repulsion when an electron is added. Memorize: in both Group 16 and Group 17, the second-row element loses to its third-row cousin in .
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