JEE Main · 2021 · Shift-IIeasyPERI-080

The correct order of electron gain enthalpy is:

Classification of Elements & Periodicity · Class 11 · JEE Main Previous Year Question

Question

The correct order of electron gain enthalpy is:

Options
  1. a

    \ceS>\ceO>\ceSe>\ceTe\ce{S} > \ce{O} > \ce{Se} > \ce{Te}

  2. b

    \ceO>\ceS>\ceSe>\ceTe\ce{O} > \ce{S} > \ce{Se} > \ce{Te}

  3. c

    \ceS>\ceSe>\ceTe>\ceO\ce{S} > \ce{Se} > \ce{Te} > \ce{O}

  4. d

    \ceTe>\ceSe>\ceS>\ceO\ce{Te} > \ce{Se} > \ce{S} > \ce{O}

Correct Answerc

\ceS>\ceSe>\ceTe>\ceO\ce{S} > \ce{Se} > \ce{Te} > \ce{O}

Detailed Solution

🧠 S beats O for electron gain — O's 2p2p orbital is too small, the new electron faces too much repulsion Same story as F vs Cl in halogens. The Period 2 element of any group that gains electrons (O, F) is unusually CRAMPED. Adding an extra electron to a tiny 2p2p shell raises repulsion. The Period 3 cousin (S, Cl) wins for electron gain enthalpy.

🗺️ Compare Group 16 values (kJ/mol) \ceS=200\ce{S} = -200 — most exothermic in this set. \ceSe=195\ce{Se} = -195. \ceTe=190\ce{Te} = -190. \ceO=141\ce{O} = -141 — anomalously LOW because of 2p2p repulsion.

Order by magnitude (most to least): S > Se > Te > O.

⚠️ The trap Option (b) puts O at the top: \ceO>\ceS>\ceSe>\ceTe\ce{O} > \ce{S} > \ce{Se} > \ce{Te}. This is the "expected" group trend without applying the Period 2 anomaly. The smaller atom should win, students think — but for O, the smallness causes too much repulsion when an electron is added. Memorize: in both Group 16 and Group 17, the second-row element loses to its third-row cousin in ΔegH|\Delta_{eg}H|.

Answer: (c)\boxed{\text{Answer: (c)}}

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