The correct order of first ionization enthalpy values of the following elements is: (A) O (B) N (C) Be (D) F (E) B
Classification of Elements & Periodicity · Class 11 · JEE Main Previous Year Question
The correct order of first ionization enthalpy values of the following elements is:
(A) O (B) N (C) Be (D) F (E) B
- a✓
E < C < A < B < D
- b
C < E < A < B < D
- c
B < D < C < E < A
- d
A < B < D < C < E
E < C < A < B < D
🧠 Period 2 IE has two famous exceptions: Be > B, and N > O The general trend is "IE rises across a period", but two anomalies break it. Be ( filled) is more stable than B ( alone). N ( half-filled) is more stable than O ( paired). You must apply both.
🗺️ Map letters to elements first A = O, B = N, C = Be, D = F, E = B (boron). Translation step is essential — students who skip it always pick a wrong order.
Now build the chemistry order: B (boron, ) — easiest to ionize, smallest IE. Be ( filled) — beats B. So Be > B. O (, pairing repulsion) — easier than N. N ( half-filled) — hardest in this set except F. F (, highest Z) — largest IE.
Chemistry order (low → high): B < Be < O < N < F.

Translate back to letters: E < C < A < B < D.
⚠️ The trap Option (b) C < E < A < B < D puts Be (C) below B (E) — that ignores the famous vs anomaly. The "natural left-to-right rise" is wrong here. Always check for filled and half-filled stability before writing any IE order in Period 2 or 3.
Practice this question with progress tracking
Want timed practice with adaptive difficulty? Solve this question (and hundreds more from Classification of Elements & Periodicity) inside The Crucible, our adaptive practice platform.
More JEE Main Classification of Elements & Periodicity PYQs
The property/properties that show irregularity in first four elements of group-17 is/are: (A) Covalent radius (B) Electron affinity (C) Ionic radius (D) First ionization energy Choose the correct…
Electronic configuration of four elements A, B, C and D are given below: (A) 1s2 2s2 2p3 (B) 1s2 2s2 2p4 (C) 1s2 2s2 2p5 (D) 1s2 2s2 2p2 Which of the following is the correct order of increasing…
The atomic number of the element from the following with lowest 1st ionisation enthalpy is:
The correct order of the first ionization enthalpy is:
The element having the highest first ionization enthalpy among Si, Al, N and C is: