JEE Main · 2024 · Shift-ImediumPERI-042

The correct order of first ionization enthalpy values of the following elements is: (A) O (B) N (C) Be (D) F (E) B

Classification of Elements & Periodicity · Class 11 · JEE Main Previous Year Question

Question

The correct order of first ionization enthalpy values of the following elements is:

(A) O (B) N (C) Be (D) F (E) B

Options
  1. a

    E < C < A < B < D

  2. b

    C < E < A < B < D

  3. c

    B < D < C < E < A

  4. d

    A < B < D < C < E

Correct Answera

E < C < A < B < D

Detailed Solution

🧠 Period 2 IE has two famous exceptions: Be > B, and N > O The general trend is "IE rises across a period", but two anomalies break it. Be (2s22s^2 filled) is more stable than B (2p12p^1 alone). N (2p32p^3 half-filled) is more stable than O (2p42p^4 paired). You must apply both.

🗺️ Map letters to elements first A = O, B = N, C = Be, D = F, E = B (boron). Translation step is essential — students who skip it always pick a wrong order.

Now build the chemistry order: B (boron, 2p12p^1) — easiest to ionize, smallest IE. Be (2s22s^2 filled) — beats B. So Be > B. O (2p42p^4, pairing repulsion) — easier than N. N (2p32p^3 half-filled) — hardest in this set except F. F (2p52p^5, highest Z) — largest IE.

Chemistry order (low → high): B < Be < O < N < F. image

Translate back to letters: E < C < A < B < D.

⚠️ The trap Option (b) C < E < A < B < D puts Be (C) below B (E) — that ignores the famous s2s^2 vs p1p^1 anomaly. The "natural left-to-right rise" is wrong here. Always check for s2s^2 filled and p3p^3 half-filled stability before writing any IE order in Period 2 or 3.

Answer: (a)\boxed{\text{Answer: (a)}}

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